(S)-(E)-tert-butyl (5-((tert-butyldiphenylsilyl)oxy)-4-methyl-1-phenylpent-3-en-2-yl)carbamate

Base Information

Chemical Name:(S)-(E)-tert-butyl (5-((tert-butyldiphenylsilyl)oxy)-4-methyl-1-phenylpent-3-en-2-yl)carbamate
CAS No.:1326776-72-0
Molecular Formula:C₃₃H₄₃NO₃Si
Molecular Weight:529.795
Hs Code.:

Synonyms:(S)-(E)-tert-butyl (5-((tert-butyldiphenylsilyl)oxy)-4-methyl-1-phenylpent-3-en-2-yl)carbamate

Suppliers and Price of (S)-(E)-tert-butyl (5-((tert-butyldiphenylsilyl)oxy)-4-methyl-1-phenylpent-3-en-2-yl)carbamate

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (S)-(E)-tert-butyl (5-((tert-butyldiphenylsilyl)oxy)-4-methyl-1-phenylpent-3-en-2-yl)carbamate

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Technology Process of (S)-(E)-tert-butyl (5-((tert-butyldiphenylsilyl)oxy)-4-methyl-1-phenylpent-3-en-2-yl)carbamate

There total 2 articles about (S)-(E)-tert-butyl (5-((tert-butyldiphenylsilyl)oxy)-4-methyl-1-phenylpent-3-en-2-yl)carbamate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

: 1266130-89-5
(S)-(E)-tert-butyl (5-hydroxy-4-methyl-1-phenylpent-3-en-2-yl)carbamate

: 58479-61-1
tert-butylchlorodiphenylsilane

: 1326776-72-0
(S)-(E)-tert-butyl (5-((tert-butyldiphenylsilyl)oxy)-4-methyl-1-phenylpent-3-en-2-yl)carbamate

Guidance literature:: With 1H-imidazole; In dichloromethane; at 25 ℃; for 24h; Inert atmosphere;
DOI:10.1021/jo201215c

Reference yield:

: 1326776-46-8
(S)-(E)-methyl 4-((tert-butoxycarbonyl)amino)-2-methyl-5-phenylpent-2-enoate

: 1326776-72-0
(S)-(E)-tert-butyl (5-((tert-butyldiphenylsilyl)oxy)-4-methyl-1-phenylpent-3-en-2-yl)carbamate

Guidance literature:: Multi-step reaction with 2 steps

1.1: diisobutylaluminium hydride / hexane; dichloromethane / 5 h / -50 °C / Inert atmosphere

1.2: Inert atmosphere

2.1: 1H-imidazole / dichloromethane / 24 h / 25 °C / Inert atmosphere

With 1H-imidazole; diisobutylaluminium hydride; In hexane; dichloromethane;
DOI:10.1021/jo201215c

Reference yield:

: 1326776-72-0
(S)-(E)-tert-butyl (5-((tert-butyldiphenylsilyl)oxy)-4-methyl-1-phenylpent-3-en-2-yl)carbamate

: 1326776-70-8
C₂₈H₃₅NOSi

Guidance literature:: (S)-(E)-tert-butyl (5-((tert-butyldiphenylsilyl)oxy)-4-methyl-1-phenylpent-3-en-2-yl)carbamate; With hydrogenchloride; In 1,4-dioxane; diethyl ether; at 25 ℃; for 4h; Inert atmosphere;

With sodium hydroxide; In 1,4-dioxane; diethyl ether; water; Inert atmosphere;
DOI:10.1021/jo201215c