meso-tetrakis(4-acetamidophenyl)porphyrin

Base Information

• Chemical Name: meso-tetrakis(4-acetamidophenyl)porphyrin
• CAS No.: 22220-20-8
• Molecular Formula: C₅₂H₄₂N₈O₄
• Molecular Weight: 842.957
• Mol file: 22220-20-8.mol

Synonyms:meso-tetrakis(4-acetamidophenyl)porphyrin

Chemical Property of meso-tetrakis(4-acetamidophenyl)porphyrin

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of meso-tetrakis(4-acetamidophenyl)porphyrin

There total 5 articles about meso-tetrakis(4-acetamidophenyl)porphyrin which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 65.0%

tetrakis(4-aminophenyl)porphyrin (22112-84-1) + acetyl chloride (75-36-5) → meso-tetrakis(4-acetamidophenyl)porphyrin (22220-20-8)

Guidance literature:

With triethylamine; In dichloromethane; at 0 - 20 ℃; for 13h;

DOI:10.1002/anie.202002311

Reference yield:

N-{4-[10,15,20-Tris-(4-acetylamino-phenyl)-porphyrinogen-5-yl]-phenyl}-acetamide → meso-tetrakis(4-acetamidophenyl)porphyrin (22220-20-8)

Guidance literature:

With chloranil; In tetrahydrofuran; water; Yield given;

DOI:10.1021/jo9600161

Reference yield:

para-acetamidobenzaldehyde (122-85-0) → meso-tetrakis(4-acetamidophenyl)porphyrin (22220-20-8)

Guidance literature:

Multi-step reaction with 2 steps

1: aq. sodium dodecyl sulfate, HCl / 5 h

2: 2,3,5,6-tetrachloro-1,4-benzoquinone / H₂O; tetrahydrofuran

With hydrogenchloride; sodium dodecyl-sulfate; chloranil; In tetrahydrofuran; water;

DOI:10.1021/jo9600161

upstream raw materials:

pyrrole

para-acetamidobenzaldehyde

tetrakis(4-aminophenyl)porphyrin

acetyl chloride

Refernces

• 1、 Bonar-Law, Richard P.. "Porphyrin synthesis in surfactant solution: Multicomponent assembly in micelles". . p. 3623 - 3634. Retrieved 2007/10/03.