N'-(1'',10''-phenantroline-5''-yl)-N-(2'-ethylhexyl)-1,6,7,12-tetrakis-[4'(1'',1'',3'',3''-tetramethylbutyl)phenoxy]-perylene-3,4:9,10-tetracarboximide

Base Information

• Chemical Name: N'-(1'',10''-phenantroline-5''-yl)-N-(2'-ethylhexyl)-1,6,7,12-tetrakis-[4'(1'',1'',3'',3''-tetramethylbutyl)phenoxy]-perylene-3,4:9,10-tetracarboximide
• CAS No.: 1182346-96-8
• Molecular Formula: C₁₀₀H₁₁₂N₄O₈
• Molecular Weight: 1498.01
• Mol file: 1182346-96-8.mol

Synonyms:N'-(1'',10''-phenantroline-5''-yl)-N-(2'-ethylhexyl)-1,6,7,12-tetrakis-[4'(1'',1'',3'',3''-tetramethylbutyl)phenoxy]-perylene-3,4:9,10-tetracarboximide

Chemical Property of N'-(1'',10''-phenantroline-5''-yl)-N-(2'-ethylhexyl)-1,6,7,12-tetrakis-[4'(1'',1'',3'',3''-tetramethylbutyl)phenoxy]-perylene-3,4:9,10-tetracarboximide

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of N'-(1'',10''-phenantroline-5''-yl)-N-(2'-ethylhexyl)-1,6,7,12-tetrakis-[4'(1'',1'',3'',3''-tetramethylbutyl)phenoxy]-perylene-3,4:9,10-tetracarboximide

There total 1 articles about N'-(1'',10''-phenantroline-5''-yl)-N-(2'-ethylhexyl)-1,6,7,12-tetrakis-[4'(1'',1'',3'',3''-tetramethylbutyl)phenoxy]-perylene-3,4:9,10-tetracarboximide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

1,10-phenanthroline-5-amine (54258-41-2) + N-(2'-ethylhexyl)-1,6,7,12-tetrakis-[4'-(1'',1'',3'',3''-tetramethylbutyl)phenoxy]perylene-9,10-dicarboximide-3,4-dicarboxyanhydride → N'-(1'',10''-phenantroline-5''-yl)-N-(2'-ethylhexyl)-1,6,7,12-tetrakis-[4'(1'',1'',3'',3''-tetramethylbutyl)phenoxy]-perylene-3,4:9,10-tetracarboximide (1182346-96-8)

Guidance literature:

With quinoline; zinc diacetate; at 180 ℃; for 10h;

DOI:10.1039/b905367k

Reference yield: 55.0%

[iridium(III)(μ-chloro)(2-phenylpyridine)2]2 + N'-(1'',10''-phenantroline-5''-yl)-N-(2'-ethylhexyl)-1,6,7,12-tetrakis-[4'(1'',1'',3'',3''-tetramethylbutyl)phenoxy]-perylene-3,4:9,10-tetracarboximide (1182346-96-8) + hexafluorophosphate anion → (((CH3)3CCH2C(CH3)2C6H4O)2C10H2(CO)2N)2(CH2CHC2H5C4H9)(C12H7N2)Ir(C6H4C5H4N)2(1+)*PF6(1-)=C100H112N4O8Ir(C6H4C5H4N)2PF6

Guidance literature:

In ethylene glycol; Ir complex and ligand refluxed in ethylene glycol for 15 h;

DOI:10.1039/b905367k

upstream raw materials:

1,10-phenanthroline-5-amine