N,N',N''-(nitrilotri-2,1-ethanediyl)tris(2,2'-dihydroxy-4-biphenylcarboxamide)

Base Information

Chemical Name:N,N',N''-(nitrilotri-2,1-ethanediyl)tris(2,2'-dihydroxy-4-biphenylcarboxamide)
CAS No.:208399-31-9
Molecular Formula:C₄₅H₄₂N₄O₉
Molecular Weight:782.85
Hs Code.:

Synonyms:N,N',N''-(nitrilotri-2,1-ethanediyl)tris(2,2'-dihydroxy-4-biphenylcarboxamide)

Suppliers and Price of N,N',N''-(nitrilotri-2,1-ethanediyl)tris(2,2'-dihydroxy-4-biphenylcarboxamide)

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of N,N',N''-(nitrilotri-2,1-ethanediyl)tris(2,2'-dihydroxy-4-biphenylcarboxamide)

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of N,N',N''-(nitrilotri-2,1-ethanediyl)tris(2,2'-dihydroxy-4-biphenylcarboxamide)

There total 11 articles about N,N',N''-(nitrilotri-2,1-ethanediyl)tris(2,2'-dihydroxy-4-biphenylcarboxamide) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 208399-30-8
N,N',N''-(nitrilotri-2,1-ethanediyl)tris(2,2'-dimethoxy-4-biphenylcarboxamide)

: 208399-31-9
N,N',N''-(nitrilotri-2,1-ethanediyl)tris(2,2'-dihydroxy-4-biphenylcarboxamide)

Guidance literature:: With boron tribromide; In dichloromethane; for 12h; Ambient temperature; 1.) 0 deg C;
DOI:10.1002/(SICI)1099-0682(199805)1998:5<613::AID-EJIC613>3.0.CO;2-L

Reference yield:

: 38512-82-2
3-methoxy-4-nitrotoluene

: 208399-31-9
N,N',N''-(nitrilotri-2,1-ethanediyl)tris(2,2'-dihydroxy-4-biphenylcarboxamide)

Guidance literature:: Multi-step reaction with 9 steps

1: 73 percent / potassium permanganate, sodium hydrogen carbonate / H₂O / 4 h / Heating

2: 91 percent / BF₃ / 12 h

3: 91 percent / hydrogen / 10percent Pd/C / CH₂Cl₂; ethanol / 12 h

4: 20percent H₂SO₄, sodium nitrite / H₂O / 0 °C

5: KI / H₂O / 2 h / 50 °C

6: 97 percent / Et₃N, Pd(OAc)2, P(o-Tol)3 / dimethylformamide / 3 h / 100 °C

7: KOH / ethanol / 3 h / Heating

8: 1.) N,N'-carbonyldiimidazole / 1.) THF, 12 h; 2.) room temp., overnight

9: 90 percent / 1.) BBr₃ / CH₂Cl₂ / 12 h / Ambient temperature; 1.) 0 deg C

With palladium diacetate; potassium hydroxide; potassium permanganate; sulfuric acid; boron trifluoride; hydrogen; boron tribromide; sodium hydrogencarbonate; triethylamine; tris-(o-tolyl)phosphine; 1,1'-carbonyldiimidazole; potassium iodide; sodium nitrite; palladium on activated charcoal; In ethanol; dichloromethane; water; N,N-dimethyl-formamide;
DOI:10.1002/(SICI)1099-0682(199805)1998:5<613::AID-EJIC613>3.0.CO;2-L

Reference yield:

: 5081-36-7
3-methoxy-4-nitrobenzoic acid

: 208399-31-9
N,N',N''-(nitrilotri-2,1-ethanediyl)tris(2,2'-dihydroxy-4-biphenylcarboxamide)

Guidance literature:: Multi-step reaction with 8 steps

1: 91 percent / BF₃ / 12 h

2: 91 percent / hydrogen / 10percent Pd/C / CH₂Cl₂; ethanol / 12 h

3: 20percent H₂SO₄, sodium nitrite / H₂O / 0 °C

4: KI / H₂O / 2 h / 50 °C

5: 97 percent / Et₃N, Pd(OAc)2, P(o-Tol)3 / dimethylformamide / 3 h / 100 °C

6: KOH / ethanol / 3 h / Heating

7: 1.) N,N'-carbonyldiimidazole / 1.) THF, 12 h; 2.) room temp., overnight

8: 90 percent / 1.) BBr₃ / CH₂Cl₂ / 12 h / Ambient temperature; 1.) 0 deg C

With palladium diacetate; potassium hydroxide; sulfuric acid; boron trifluoride; hydrogen; boron tribromide; triethylamine; tris-(o-tolyl)phosphine; 1,1'-carbonyldiimidazole; potassium iodide; sodium nitrite; palladium on activated charcoal; In ethanol; dichloromethane; water; N,N-dimethyl-formamide;
DOI:10.1002/(SICI)1099-0682(199805)1998:5<613::AID-EJIC613>3.0.CO;2-L