N,N',N''-(nitrilotri-2,1-ethanediyl)tris(2,2'-dimethoxy-4-biphenylcarboxamide)

Base Information

Chemical Name:N,N',N''-(nitrilotri-2,1-ethanediyl)tris(2,2'-dimethoxy-4-biphenylcarboxamide)
CAS No.:208399-30-8
Molecular Formula:C₅₁H₅₄N₄O₉
Molecular Weight:867.011
Hs Code.:

Synonyms:N,N',N''-(nitrilotri-2,1-ethanediyl)tris(2,2'-dimethoxy-4-biphenylcarboxamide)

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Chemical Property of N,N',N''-(nitrilotri-2,1-ethanediyl)tris(2,2'-dimethoxy-4-biphenylcarboxamide)

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Technology Process of N,N',N''-(nitrilotri-2,1-ethanediyl)tris(2,2'-dimethoxy-4-biphenylcarboxamide)

There total 10 articles about N,N',N''-(nitrilotri-2,1-ethanediyl)tris(2,2'-dimethoxy-4-biphenylcarboxamide) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 38512-82-2
3-methoxy-4-nitrotoluene

: 208399-30-8
N,N',N''-(nitrilotri-2,1-ethanediyl)tris(2,2'-dimethoxy-4-biphenylcarboxamide)

Guidance literature:: Multi-step reaction with 8 steps

1: 73 percent / potassium permanganate, sodium hydrogen carbonate / H₂O / 4 h / Heating

2: 91 percent / BF₃ / 12 h

3: 91 percent / hydrogen / 10percent Pd/C / CH₂Cl₂; ethanol / 12 h

4: 20percent H₂SO₄, sodium nitrite / H₂O / 0 °C

5: KI / H₂O / 2 h / 50 °C

6: 97 percent / Et₃N, Pd(OAc)2, P(o-Tol)3 / dimethylformamide / 3 h / 100 °C

7: KOH / ethanol / 3 h / Heating

8: 1.) N,N'-carbonyldiimidazole / 1.) THF, 12 h; 2.) room temp., overnight

With palladium diacetate; potassium hydroxide; potassium permanganate; sulfuric acid; boron trifluoride; hydrogen; sodium hydrogencarbonate; triethylamine; tris-(o-tolyl)phosphine; 1,1'-carbonyldiimidazole; potassium iodide; sodium nitrite; palladium on activated charcoal; In ethanol; dichloromethane; water; N,N-dimethyl-formamide;
DOI:10.1002/(SICI)1099-0682(199805)1998:5<613::AID-EJIC613>3.0.CO;2-L

Reference yield:

: 5081-36-7
3-methoxy-4-nitrobenzoic acid

: 208399-30-8
N,N',N''-(nitrilotri-2,1-ethanediyl)tris(2,2'-dimethoxy-4-biphenylcarboxamide)

Guidance literature:: Multi-step reaction with 7 steps

1: 91 percent / BF₃ / 12 h

2: 91 percent / hydrogen / 10percent Pd/C / CH₂Cl₂; ethanol / 12 h

3: 20percent H₂SO₄, sodium nitrite / H₂O / 0 °C

4: KI / H₂O / 2 h / 50 °C

5: 97 percent / Et₃N, Pd(OAc)2, P(o-Tol)3 / dimethylformamide / 3 h / 100 °C

6: KOH / ethanol / 3 h / Heating

7: 1.) N,N'-carbonyldiimidazole / 1.) THF, 12 h; 2.) room temp., overnight

With palladium diacetate; potassium hydroxide; sulfuric acid; boron trifluoride; hydrogen; triethylamine; tris-(o-tolyl)phosphine; 1,1'-carbonyldiimidazole; potassium iodide; sodium nitrite; palladium on activated charcoal; In ethanol; dichloromethane; water; N,N-dimethyl-formamide;
DOI:10.1002/(SICI)1099-0682(199805)1998:5<613::AID-EJIC613>3.0.CO;2-L

Reference yield:

: 5081-37-8
methyl 3-methoxy-4-nitrobenzoate

: 208399-30-8
N,N',N''-(nitrilotri-2,1-ethanediyl)tris(2,2'-dimethoxy-4-biphenylcarboxamide)

Guidance literature:: Multi-step reaction with 6 steps

1: 91 percent / hydrogen / 10percent Pd/C / CH₂Cl₂; ethanol / 12 h

2: 20percent H₂SO₄, sodium nitrite / H₂O / 0 °C

3: KI / H₂O / 2 h / 50 °C

4: 97 percent / Et₃N, Pd(OAc)2, P(o-Tol)3 / dimethylformamide / 3 h / 100 °C

5: KOH / ethanol / 3 h / Heating

6: 1.) N,N'-carbonyldiimidazole / 1.) THF, 12 h; 2.) room temp., overnight

With palladium diacetate; potassium hydroxide; sulfuric acid; hydrogen; triethylamine; tris-(o-tolyl)phosphine; 1,1'-carbonyldiimidazole; potassium iodide; sodium nitrite; palladium on activated charcoal; In ethanol; dichloromethane; water; N,N-dimethyl-formamide;
DOI:10.1002/(SICI)1099-0682(199805)1998:5<613::AID-EJIC613>3.0.CO;2-L