(4S,5R)-4,5-Bis-(tert-butyl-dimethyl-silanyloxymethyl)-1,2-bis-trimethylsilanylmethyl-cyclohexene

Base Information

Chemical Name:(4S,5R)-4,5-Bis-(tert-butyl-dimethyl-silanyloxymethyl)-1,2-bis-trimethylsilanylmethyl-cyclohexene
CAS No.:87432-57-3
Molecular Formula:C₂₈H₆₂O₂Si₄
Molecular Weight:543.141
Hs Code.:

Synonyms:(4S,5R)-4,5-Bis-(tert-butyl-dimethyl-silanyloxymethyl)-1,2-bis-trimethylsilanylmethyl-cyclohexene

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (4S,5R)-4,5-Bis-(tert-butyl-dimethyl-silanyloxymethyl)-1,2-bis-trimethylsilanylmethyl-cyclohexene

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Technology Process of (4S,5R)-4,5-Bis-(tert-butyl-dimethyl-silanyloxymethyl)-1,2-bis-trimethylsilanylmethyl-cyclohexene

There total 2 articles about (4S,5R)-4,5-Bis-(tert-butyl-dimethyl-silanyloxymethyl)-1,2-bis-trimethylsilanylmethyl-cyclohexene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

: 18162-48-6
tert-butyldimethylsilyl chloride

: 87413-55-6
((1S,6R)-6-Hydroxymethyl-3,4-bis-trimethylsilanylmethyl-cyclohex-3-enyl)-methanol

: 87432-57-3
(4S,5R)-4,5-Bis-(tert-butyl-dimethyl-silanyloxymethyl)-1,2-bis-trimethylsilanylmethyl-cyclohexene

Guidance literature:: With C₃H₄N₂; In N,N-dimethyl-formamide;
DOI:10.1021/ja00360a057

Reference yield:

: 82167-48-4
2,3-bis<(trimethyksilyl)methyl>-1,3-butadiene

: 87432-57-3
(4S,5R)-4,5-Bis-(tert-butyl-dimethyl-silanyloxymethyl)-1,2-bis-trimethylsilanylmethyl-cyclohexene

Guidance literature:: Multi-step reaction with 2 steps

1: 2.) LAH / 1.) PhCH₃, heating, 2.) THF, reflux

2: 99 percent / C₃H₄N₂ / dimethylformamide

With lithium aluminium tetrahydride; In N,N-dimethyl-formamide;
DOI:10.1021/ja00360a057

Reference yield:

: 87432-57-3
(4S,5R)-4,5-Bis-(tert-butyl-dimethyl-silanyloxymethyl)-1,2-bis-trimethylsilanylmethyl-cyclohexene

: 87432-56-2
(5S,6R)-2,2-Bis-benzenesulfonyl-5,6-bis-(tert-butyl-dimethyl-silanyloxymethyl)-2,3,4,5,6,7-hexahydro-1H-indene

Guidance literature:: Multi-step reaction with 2 steps

1: 1.) cupric bromide, propylene oxide, bromine, 2.) bromine / 1.) CCl₄, THF, -78 deg C, 15 min, to 0 deg C, 15 min, 2.) CCl₄, -78 deg C, 15 min, to 0 deg C, 15 min

2: 80 percent / sodium hydride / dimethylformamide

With bromine; sodium hydride; methyloxirane; copper(ll) bromide; In N,N-dimethyl-formamide;
DOI:10.1021/ja00360a057