1,1,1,2,2,2,3,3,3-nonacarbonyl-1,2-[μ-bis(diphenylphosphino)methane-P',P'']-3-(trimethyl phosphite-P)-triangulotriruthenium(0)

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Chemical Name:1,1,1,2,2,2,3,3,3-nonacarbonyl-1,2-[μ-bis(diphenylphosphino)methane-P',P'']-3-(trimethyl phosphite-P)-triangulotriruthenium(0)
CAS No.:155706-55-1
Molecular Formula:C₃₇H₃₁O₁₂P₃Ru₃
Molecular Weight:1063.78
Hs Code.:

Synonyms:1,1,1,2,2,2,3,3,3-nonacarbonyl-1,2-[μ-bis(diphenylphosphino)methane-P',P'']-3-(trimethyl phosphite-P)-triangulotriruthenium(0)

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Chemical Property of 1,1,1,2,2,2,3,3,3-nonacarbonyl-1,2-[μ-bis(diphenylphosphino)methane-P',P'']-3-(trimethyl phosphite-P)-triangulotriruthenium(0)

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Technology Process of 1,1,1,2,2,2,3,3,3-nonacarbonyl-1,2-[μ-bis(diphenylphosphino)methane-P',P'']-3-(trimethyl phosphite-P)-triangulotriruthenium(0)

There total 2 articles about 1,1,1,2,2,2,3,3,3-nonacarbonyl-1,2-[μ-bis(diphenylphosphino)methane-P',P'']-3-(trimethyl phosphite-P)-triangulotriruthenium(0) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 65.0%

: 64364-79-0
Ru3(CO)10(μ-bis(diphenylphosphino)methane)

: 121-45-9
phosphorous acid trimethyl ester

: 155706-55-1
1,1,1,2,2,2,3,3,3-nonacarbonyl-1,2-[μ-bis(diphenylphosphino)methane-P',P'']-3-(trimethyl phosphite-P)-triangulotriruthenium(0)

Guidance literature:: With Me₃NO; In dichloromethane; N2, Me3NO added to a stirred soln. of Ru-compound and P(OMe)3; solvent removed, extrd. (CH2Cl2), evapd. to dryness, recrystd. (CH2Cl2/MeOH); elem. anal.;

Reference yield:

: {decacarbonyl(μ-bis(diphenylphosphino)methane)triruthenium}

: 121-45-9
phosphorous acid trimethyl ester

: 155706-55-1
1,1,1,2,2,2,3,3,3-nonacarbonyl-1,2-[μ-bis(diphenylphosphino)methane-P',P'']-3-(trimethyl phosphite-P)-triangulotriruthenium(0)

Guidance literature:: With diphenylketyl radical; In tetrahydrofuran; N2-atmosphere; treatment equimolar amts. with diphenylketyl radical; TLC, recrystn. (CH2Cl2/MeOH);
DOI:10.1107/S0108270197014881