diphenylmethanone O-[(2E)-3-phenylprop-2-enyl] oxime

Base Information

• Chemical Name: diphenylmethanone O-[(2E)-3-phenylprop-2-enyl] oxime
• CAS No.: 163224-08-6
• Molecular Formula: C₂₂H₁₉NO
• Molecular Weight: 313.399
• Mol file: 163224-08-6.mol

Synonyms:diphenylmethanone O-[(2E)-3-phenylprop-2-enyl] oxime

Chemical Property of diphenylmethanone O-[(2E)-3-phenylprop-2-enyl] oxime

Chemical Property:

Purity/Quality:

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MSDS Files:

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Technology Process of diphenylmethanone O-[(2E)-3-phenylprop-2-enyl] oxime

There total 3 articles about diphenylmethanone O-[(2E)-3-phenylprop-2-enyl] oxime which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

Benzophenone oxime (574-66-3) + 1-phenyl-2-propenyl acetate (7217-71-2) → diphenylmethanone O-[(2E)-3-phenylprop-2-enyl] oxime (163224-08-6)

Guidance literature:

With diethylzinc; tetrakis(triphenylphosphine) palladium⁽⁰⁾; In tetrahydrofuran; hexane; at 20 ℃; for 15h;

DOI:10.1021/jo050632+

Reference yield:

Benzophenone oxime (574-66-3) + (E)-cinnamyl diethyl phosphate (85669-63-2) → diphenylmethanone O-[(2E)-3-phenylprop-2-enyl] oxime (163224-08-6) + benzophenone O-[(R)-1-phenylprop-2-enyl]oxime + benzophenone O-[(S)-1-phenylprop-2-enyl]oxime

Guidance literature:

With barium dihydroxide; bis(1,5-cyclooctadiene)diiridium(I) dichloride; (S,S)-2,6-bis(4-phenyl-2-oxazolinyl)pyridine; In dichloromethane; at -20 ℃; for 40h; Title compound not separated from byproducts;

DOI:10.1021/ol047915t

Reference yield:

Benzophenone oxime (574-66-3) → diphenylmethanone O-[(2E)-3-phenylprop-2-enyl] oxime (163224-08-6)

Guidance literature:

With sodium hydride; In tetrahydrofuran;

DOI:10.1039/c39950000235

upstream raw materials:

Benzophenone oxime

1-phenyl-2-propenyl acetate

(E)-cinnamyl diethyl phosphate

Downstream raw materials:

benzophenone