methyl dimethylthexylsilyl 2-O-acetyl-4-O-(2-azido-6-O-benzoyl-3,4-di-O-benzyl-2-deoxy-α-D-glucopyranosyl)-3-O-benzyl-β-L-idopyranuronate

Base Information

Chemical Name:methyl dimethylthexylsilyl 2-O-acetyl-4-O-(2-azido-6-O-benzoyl-3,4-di-O-benzyl-2-deoxy-α-D-glucopyranosyl)-3-O-benzyl-β-L-idopyranuronate
CAS No.:496780-25-7
Molecular Formula:C₅₁H₆₃N₃O₁₃Si
Molecular Weight:954.159
Hs Code.:

Synonyms:methyl dimethylthexylsilyl 2-O-acetyl-4-O-(2-azido-6-O-benzoyl-3,4-di-O-benzyl-2-deoxy-α-D-glucopyranosyl)-3-O-benzyl-β-L-idopyranuronate

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Chemical Property of methyl dimethylthexylsilyl 2-O-acetyl-4-O-(2-azido-6-O-benzoyl-3,4-di-O-benzyl-2-deoxy-α-D-glucopyranosyl)-3-O-benzyl-β-L-idopyranuronate

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Technology Process of methyl dimethylthexylsilyl 2-O-acetyl-4-O-(2-azido-6-O-benzoyl-3,4-di-O-benzyl-2-deoxy-α-D-glucopyranosyl)-3-O-benzyl-β-L-idopyranuronate

There total 1 articles about methyl dimethylthexylsilyl 2-O-acetyl-4-O-(2-azido-6-O-benzoyl-3,4-di-O-benzyl-2-deoxy-α-D-glucopyranosyl)-3-O-benzyl-β-L-idopyranuronate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 43.0%

: 108-24-7
acetic anhydride

: 243982-79-8
methyl (dimethylthexylsilyl 3-O-benzyl-β-L-idopyranoside)uronate

: 496780-24-6
2-azido-6-O-benzoyl-3,4-di-O-benzyl-2-deoxy-α,β-D-glucopyranose trichloroacetimidate

: 496780-25-7
methyl dimethylthexylsilyl 2-O-acetyl-4-O-(2-azido-6-O-benzoyl-3,4-di-O-benzyl-2-deoxy-α-D-glucopyranosyl)-3-O-benzyl-β-L-idopyranuronate

Guidance literature:: methyl (dimethylthexylsilyl 3-O-benzyl-β-L-idopyranoside)uronate; 2-azido-6-O-benzoyl-3,4-di-O-benzyl-2-deoxy-α,β-D-glucopyranose trichloroacetimidate; With trimethylsilyl trifluoromethanesulfonate; In dichloromethane; at 0 ℃; for 0.5h;

acetic anhydride; With pyridine; for 24h;
DOI:10.1139/v02-023

Reference yield: 68.0%

: 507-09-5
tiolacetic acid

: 496780-25-7
methyl dimethylthexylsilyl 2-O-acetyl-4-O-(2-azido-6-O-benzoyl-3,4-di-O-benzyl-2-deoxy-α-D-glucopyranosyl)-3-O-benzyl-β-L-idopyranuronate

: 496780-26-8
methyl dimethylthexylsilyl 4-O-(2-acetamido-6-O-benzoyl-3,4-di-O-benzyl-2-deoxy-α-D-glucopyranosyl)-2-O-acetyl-3-O-benzyl-β-L-idopyranuronate

Guidance literature:: at 20 ℃; for 30h;
DOI:10.1139/v02-023

Reference yield:

: 496780-25-7
methyl dimethylthexylsilyl 2-O-acetyl-4-O-(2-azido-6-O-benzoyl-3,4-di-O-benzyl-2-deoxy-α-D-glucopyranosyl)-3-O-benzyl-β-L-idopyranuronate

: methyl 4-O-(2-acetamido-6-O-benzoyl-3,4-di-O-benzyl-2-deoxy-α-D-glucopyranosyl)-2-O-acetyl-3-O-benzyl-α-L-idopyranuronate

Guidance literature:: Multi-step reaction with 2 steps

1: 68 percent / 30 h / 20 °C

2: pyridinium hydrofluoride / tetrahydrofuran / 24 h / 0 °C

With pyridine hydrogenfluoride; In tetrahydrofuran;
DOI:10.1139/v02-023