[5-(diphenylthiophosphoryl)-10,15,20-tris(3,5-di-tert-butylphenyl)porphyrinato]zinc(II)

Base Information

• Chemical Name: [5-(diphenylthiophosphoryl)-10,15,20-tris(3,5-di-tert-butylphenyl)porphyrinato]zinc(II)
• CAS No.: 910135-20-5
• Molecular Formula: C₇₄H₈₁N₄PSZn
• Molecular Weight: 1154.91

Synonyms:[5-(diphenylthiophosphoryl)-10,15,20-tris(3,5-di-tert-butylphenyl)porphyrinato]zinc(II)

Chemical Property of [5-(diphenylthiophosphoryl)-10,15,20-tris(3,5-di-tert-butylphenyl)porphyrinato]zinc(II)

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Technology Process of [5-(diphenylthiophosphoryl)-10,15,20-tris(3,5-di-tert-butylphenyl)porphyrinato]zinc(II)

There total 2 articles about [5-(diphenylthiophosphoryl)-10,15,20-tris(3,5-di-tert-butylphenyl)porphyrinato]zinc(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

sulfur (10544-50-0) + [5-iodo-10,15,20-tris(3,5-di-tert-butylphenyl)porphyrinato]zinc(II) (220355-80-6) + diphenylphosphane (829-85-6) → [5-(diphenylthiophosphoryl)-10,15,20-tris(3,5-di-tert-butylphenyl)porphyrinato]zinc(II) (910135-20-5)

Guidance literature:

With triethyl amine; palladium diacetate; In tetrahydrofuran; acetonitrile; 1. cat. Pd(CH3CO2)2, (C6H5)2PH, (C2H5)3N, CH3CN-THF; 2. S8;

DOI:10.1021/ja710542e

Reference yield:

[5-(diphenylphosphanyl)-10,15,20-tris(3,5-di-tert-butylphenyl)porphyrinato]zinc(II) (1019849-49-0) → [5-(diphenylthiophosphoryl)-10,15,20-tris(3,5-di-tert-butylphenyl)porphyrinato]zinc(II) (910135-20-5)

Guidance literature:

With sulfur; In tetrahydrofuran; acetonitrile; for 0.5h; Inert atmosphere;

DOI:10.1021/ja210205v

Reference yield: 90.0%

[5-(diphenylthiophosphoryl)-10,15,20-tris(3,5-di-tert-butylphenyl)porphyrinato]zinc(II) (910135-20-5) → [5-(diphenylphosphanyl)-10,15,20-tris(3,5-di-tert-butylphenyl)porphyrinato]zinc(II) (1019849-49-0)

Guidance literature:

With P(N(CH₃)2)3; In toluene; excess of P(N(CH3)2)3 in refluxing toluene; pptn. under inert atm.;

DOI:10.1021/ja710542e

upstream raw materials:

sulfur

[5-iodo-10,15,20-tris(3,5-di-tert-butylphenyl)porphyrinato]zinc(II)

diphenylphosphane

[5-(diphenylphosphanyl)-10,15,20-tris(3,5-di-tert-butylphenyl)porphyrinato]zinc(II)

Downstream raw materials:

[5-(diphenylphosphanyl)-10,15,20-tris(3,5-di-tert-butylphenyl)porphyrinato]zinc(II)

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