[5-(diphenylphosphanyl)-10,15,20-tris(3,5-di-tert-butylphenyl)porphyrinato]zinc(II)

Base Information

• Chemical Name: [5-(diphenylphosphanyl)-10,15,20-tris(3,5-di-tert-butylphenyl)porphyrinato]zinc(II)
• CAS No.: 1019849-49-0
• Molecular Formula: C₇₄H₈₁N₄PZn
• Molecular Weight: 1122.85

Synonyms:[5-(diphenylphosphanyl)-10,15,20-tris(3,5-di-tert-butylphenyl)porphyrinato]zinc(II)

Chemical Property of [5-(diphenylphosphanyl)-10,15,20-tris(3,5-di-tert-butylphenyl)porphyrinato]zinc(II)

Chemical Property:

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Technology Process of [5-(diphenylphosphanyl)-10,15,20-tris(3,5-di-tert-butylphenyl)porphyrinato]zinc(II)

There total 2 articles about [5-(diphenylphosphanyl)-10,15,20-tris(3,5-di-tert-butylphenyl)porphyrinato]zinc(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

[5-(diphenylthiophosphoryl)-10,15,20-tris(3,5-di-tert-butylphenyl)porphyrinato]zinc(II) (910135-20-5) → [5-(diphenylphosphanyl)-10,15,20-tris(3,5-di-tert-butylphenyl)porphyrinato]zinc(II) (1019849-49-0)

Guidance literature:

With P(N(CH₃)2)3; In toluene; excess of P(N(CH3)2)3 in refluxing toluene; pptn. under inert atm.;

DOI:10.1021/ja710542e

Reference yield:

[5-iodo-10,15,20-tris(3,5-di-tert-butylphenyl)porphyrinato]zinc(II) (220355-80-6) + diphenylphosphane (829-85-6) → [5-(diphenylphosphanyl)-10,15,20-tris(3,5-di-tert-butylphenyl)porphyrinato]zinc(II) (1019849-49-0)

Guidance literature:

With palladium diacetate; triethylamine; In tetrahydrofuran; acetonitrile; at 80 ℃; for 11h; Inert atmosphere;

DOI:10.1021/ja210205v

Reference yield: 73.0%

[5-(diphenylphosphanyl)-10,15,20-tris(3,5-di-tert-butylphenyl)porphyrinato]zinc(II) (1019849-49-0) + palladium diacetate (3375-31-3) → Pd(C20H7N4(C6H3(C4H9)2)3P(C6H5)2Zn)2 + (Pd(C20H7N4(C6H3(C4H9)2)3P(C6H5)2Zn(CH3CO2)))2 (1019849-51-4)

Guidance literature:

In toluene; complex:Pd-salt 1:1, toluene, slow addn.;

DOI:10.1021/ja710542e

upstream raw materials:

[5-iodo-10,15,20-tris(3,5-di-tert-butylphenyl)porphyrinato]zinc(II)

diphenylphosphane

[5-(diphenylthiophosphoryl)-10,15,20-tris(3,5-di-tert-butylphenyl)porphyrinato]zinc(II)

Downstream raw materials:

(Pd(C₂₀H₇N₄(C₆H₃(C₄H₉)2)3P(C₆H₅)2Zn(CH₃CO₂)))2

C₂₀H₈N₄(C₆H₃(C₄H₉)2)3PO(C₆H₅)2Zn

[5-(diphenylthiophosphoryl)-10,15,20-tris(3,5-di-tert-butylphenyl)porphyrinato]zinc(II)

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