Technology Process of 1,1'-Bis(p-anisyl)-2-cymantrenyl-1-butene
There total 1 articles about 1,1'-Bis(p-anisyl)-2-cymantrenyl-1-butene which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
With
titanium tetrachloride;
In
tetrahydrofuran;
TiCl4 was added dropwise to a suspn. of Zn powder in THF at 0 °C,refluxed for 2 h, THF soln. of Mn compd. and benzophenon deriv. (molar ratio is 1:1) was added to first soln., mixt. was heated for 2 h; cooled to room temp., treated with 10 % Na2CO3 soln., extd. with ether, solvent was removed, chromy. on silica (TLC), eluent ethyl ether/pentan e 1/5, product was crystd. from ethyl ether/pentane; elem. anal.;
DOI:10.1021/ja991915k
- Guidance literature:
-
In
tetrahydrofuran;
Irradiation (UV/VIS); soln. of Mn complex in THF was irradiated in Schlenk tube; not isolated; IR monitoring;
DOI:10.1021/om010274a
- Guidance literature:
-
In
methanol; diethyl ether;
Irradiation (UV/VIS); soln. of Mn complex in diethyl ether/methanol (50/50) was irradiated in Schlenk tube for 50 min; not isolated; IR monitoring;
DOI:10.1021/om010274a
