tris(4-dibromomethyl phenyl)boroxine

Base Information

• Chemical Name: tris(4-dibromomethyl phenyl)boroxine
• CAS No.: 111561-46-7
• Molecular Formula: C₂₁H₁₅B₃Br₆O₃
• Molecular Weight: 827.205
• Mol file: 111561-46-7.mol

Synonyms:tris(4-dibromomethyl phenyl)boroxine

Chemical Property of tris(4-dibromomethyl phenyl)boroxine

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of tris(4-dibromomethyl phenyl)boroxine

There total 4 articles about tris(4-dibromomethyl phenyl)boroxine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 69.0%

N-Bromosuccinimide (128-08-5) + tris(4-bromomethyl phenyl)boroxine (51239-44-2) → tris(4-dibromomethyl phenyl)boroxine (111561-46-7)

Guidance literature:

With dibenzoyl peroxide; In tetrachloromethane; byproducts: succinimide; Irradiation (UV/VIS); 16.5g boroxine, 46.2g N-Br-succinimide, 0.4g benzoyl peroxide, 612ml CCl4, boiling while irradiation, filtration after 2.5h;; cyrstn. from the filtrate, filtration at 4°C, washing with CCl4 and petroleum ether;;

DOI:10.1021/ja01547a033

Reference yield:

tri(4-tolyl)boroxine (5084-80-0) → tris(4-dibromomethyl phenyl)boroxine (111561-46-7)

Guidance literature:

With tetrachloromethane; N-Bromosuccinimide; dibenzoyl peroxide;

DOI:10.1021/ja01547a033

Reference yield:

m-tolylboronic acid (17933-03-8) → tris(4-dibromomethyl phenyl)boroxine (111561-46-7)

Guidance literature:

Multi-step reaction with 2 steps

1: benzoyl peroxide / tetrachloromethane

2: benzoyl peroxide / tetrachloromethane

With benzoyl peroxide; In tetrachloromethane;

upstream raw materials:

4-methylphenylboronic acid

tri(4-tolyl)boroxine

N-Bromosuccinimide

tris(4-bromomethyl phenyl)boroxine

Downstream raw materials:

4-formylphenylboronic acid,