Diethyl peroxydicarbonate

Base Information

• Chemical Name: Diethyl peroxydicarbonate
• CAS No.: 14666-78-5
• Molecular Formula: C6H10 O6
• Molecular Weight: 178.142
• Hs Code.: 2909600000
• European Community (EC) Number: 238-707-3
• UN Number: 3115
• DSSTox Substance ID: DTXSID0075310
• Nikkaji Number: J241.342F
• Wikidata: Q82003297
• Mol file: 14666-78-5.mol

Synonyms:Diethyl peroxydicarbonate;ethoxycarbonyloxy ethyl carbonate;14666-78-5;Peroxydicarbonic acid, diethyl ester;EINECS 238-707-3;EC 238-707-3;Bis(ethoxyformyl) peroxide;SCHEMBL374891;DTXSID0075310;NA2175;UN2175;AKOS006280180

Chemical Property of Diethyl peroxydicarbonate

Chemical Property:

• Vapor Pressure: 1.06mmHg at 25°C
• Refractive Index: 1.5860 (estimate)
• Boiling Point: 177.1°Cat760mmHg
• Flash Point: 63.3°C
• PSA: 71.06000
• Density: 1.209g/cm³
• LogP: 1.24760
• XLogP3: 1.7
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 6
• Rotatable Bond Count: 7
• Exact Mass: 178.04773803
• Heavy Atom Count: 12
• Complexity: 136
• Transport DOT Label: Organic Peroxide

Purity/Quality:

99.9% ^*data from raw suppliers

DIETHYL PEROXYDICARBONATE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCOC(=O)OOC(=O)OCC

Technology Process of Diethyl peroxydicarbonate

There total 7 articles about Diethyl peroxydicarbonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

chloroformic acid ethyl ester (541-41-3) → Peroxydikohlensaeure-diethylester (14666-78-5)

Guidance literature:

With sodium hydroxide; dihydrogen peroxide; In water; at 5 - 10 ℃;

DOI:10.1021/ma0504522

Reference yield:

→ Peroxydikohlensaeure-diethylester (14666-78-5)

Guidance literature:

With oxygen; Petroleum ether;

Reference yield:

→ Peroxydikohlensaeure-diethylester (14666-78-5)

Guidance literature:

With oxygen; Petroleum ether;

upstream raw materials:

chloroformic acid ethyl ester

chloroform

Downstream raw materials:

2,2-bis-ethoxycarbonyloxy-5,5-dimethyl-3-morpholin-4-yl-cyclohex-3-enone

2,2,4-tris-ethoxycarbonyloxy-5,5-dimethyl-3-morpholin-4-yl-cyclohex-3-enone

2,5,8-Trioxanonanedioic acid di-2-propenyl ester

2,3-bis-(4-dichloromethyl-phenyl)-2,3-dimethyl-butane

Refernces