1-bromo-1-<<(bromomethyl)sulfonyl>methyl>-3-methylcyclohexane

Base Information

• Chemical Name: 1-bromo-1-<<(bromomethyl)sulfonyl>methyl>-3-methylcyclohexane
• CAS No.: 102683-67-0
• Molecular Formula: C₉H₁₆Br₂O₂S
• Molecular Weight: 348.099
• Mol file: 102683-67-0.mol

Synonyms:1-bromo-1-<<(bromomethyl)sulfonyl>methyl>-3-methylcyclohexane

Chemical Property of 1-bromo-1-<<(bromomethyl)sulfonyl>methyl>-3-methylcyclohexane

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1-bromo-1-<<(bromomethyl)sulfonyl>methyl>-3-methylcyclohexane

There total 1 articles about 1-bromo-1-<<(bromomethyl)sulfonyl>methyl>-3-methylcyclohexane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

bromomethanesulfonyl bromide (54730-18-6) + 1-methyl-3-methylene-cyclohexane (3101-50-6) → 1-bromo-1-<<(bromomethyl)sulfonyl>methyl>-3-methylcyclohexane (102683-67-0)

Guidance literature:

In dichloromethane; at 0 ℃;

DOI:10.1021/ja00275a051

Reference yield:

1-bromo-1-<<(bromomethyl)sulfonyl>methyl>-3-methylcyclohexane (102683-67-0) → (Z)-1-<<(bromomethyl)sulfonyl>methylene>-3-methylcyclohexane (95205-64-4) + (E)-1-<<(bromomethyl)sulfonyl>methylene>-3-methylcyclohexane (95205-63-3)

Guidance literature:

With triethylamine; In dichloromethane;

DOI:10.1021/ja00275a051

Reference yield:

1-bromo-1-<<(bromomethyl)sulfonyl>methyl>-3-methylcyclohexane (102683-67-0) → 3-methyl-1-vinylcyclohex-1-ene (95205-65-5)

Guidance literature:

Multi-step reaction with 2 steps

1: Et₃N / CH₂Cl₂

2: 77 percent / LiO-t-Bu, n-butillithium / 2-methyl-propan-2-ol; tetrahydrofuran / 1 h / Heating

With n-butyllithium; triethylamine; lithium tert-butoxide; In tetrahydrofuran; dichloromethane; tert-butyl alcohol;

DOI:10.1021/ja00275a051

upstream raw materials:

bromomethanesulfonyl bromide

1-methyl-3-methylene-cyclohexane

Downstream raw materials:

(Z)-1-<<(bromomethyl)sulfonyl>methylene>-3-methylcyclohexane

(E)-1-<<(bromomethyl)sulfonyl>methylene>-3-methylcyclohexane

3-methyl-1-vinylcyclohex-1-ene

5-Methyl-1-vinyl-1-cyclohexene