95205-65-5Relevant academic research and scientific papers
α-HALOALKANESULFONYL BROMIDES IN ORGANIC SYNTHESIS. 4. REGIOSELECTIVE γ-DEPROTONATION OF α,β-UNSATURATED SULFONES. A SIMPLE SYNTHESIS OF 2-ALKYL-1,3-BUITADIENES
Block, Eric,Eswarakrishnan, Venkatachalam,Gebreyes, Kassu
, p. 5469 - 5472 (1984)
A simple method for converting 2-methyl-1-alkenes into 2-alkyl-1,3-butadienes is described.Evidence for complexation of lithium cations by sulfonyl groups in the course of reactions of α,β-unsaturated sulfones with LiOt-Bu is presented.
Efficient synthesis of the tetracyclic aminoquinone moiety of marmycin A
Maugel, Nathan,Snider, Barry B.
supporting information; experimental part, p. 4926 - 4929 (2010/01/16)
An efficient four-step route to the tetracyclic aminoquinone moiety of marmycin A that proceeds in 41% overall yield from 5-nitronaphthoquinone and 5-methy 1-1-vinylcyclohexene will facilitate preparation of marmycin A analogues for biological evaluation.
Enantioselective syntheses of georgyone, arborone, and structural relatives. Relevance to the molecular-level understanding of olfaction
Hong, Sungwoo,Corey
, p. 1346 - 1352 (2007/10/03)
Georgyone (1) and arborone (2), powerful woody odorants, have been synthesized enantioselectively along with their enantiomers. Several structural relatives of 1 and 2 have also been made enantioselectivity in order to probe the molecular details of the b
