TRIBUTYLTIN SALICYLATE

Base Information

• Chemical Name: TRIBUTYLTIN SALICYLATE
• CAS No.: 4342-30-7
• Molecular Formula: C19H32 O3 Sn
• Molecular Weight: 427.171
• Mol file: 4342-30-7.mol

Synonyms:Phenol,2-[[(tributylstannyl)oxy]carbonyl]- (9CI); Stannane, tributyl(salicyloyloxy)-(8CI); Tin, tributyl(salicyloyloxy)- (7CI); Salicylic acid, tributylstannylderiv. (8CI); 2-[[(Tributylstannyl)oxy]carbonyl]phenol; Cotin 234; NSC 117176;Tributyltin o-hydroxybenzoate; Tributyltin salicylate

Chemical Property of TRIBUTYLTIN SALICYLATE

Chemical Property:

• Boiling Point: °Cat760mmHg
• Flash Point: °C
• PSA: 46.53000
• Density: g/cm³
• LogP: 5.89480

Purity/Quality:

98%min ^*data from raw suppliers

TRIBUTYLSTANNYL-2-HYDROXYBENZOATE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s): A poison by ingestion. Tributyl tin compounds are extremely toxic to marine life. TWA 0.1 mg(Sn)/m³; STEL 0.2 mg(Sn)/m³ (skin).
• Hazard Codes: A poison by ingestion. Tributyl tin compounds are extremely toxic to marine life. TWA 0.1 mg(Sn)/m3; STEL 0.2 mg(Sn)/m3 (skin).

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

Technology Process of TRIBUTYLTIN SALICYLATE

There total 4 articles about TRIBUTYLTIN SALICYLATE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

bis(tri-n-butyltin)oxide (56-35-9) + salicylic acid (69-72-7,25496-36-0,8052-31-1) → tributyltin salicylate (4342-30-7)

Guidance literature:

In neat (no solvent); byproducts: H2O; 1:2 mole ratio; 95-120°C;

Reference yield: 74.0%

tributyltin chloride (1461-22-9) + salicylaldehyde (90-02-8) → tributyltin salicylate (4342-30-7)

Guidance literature:

With 3-(2,6-diisopropylphenyl)-4,5-dimethylthiazol-3-ium perchlorate; oxygen; 1,8-diazabicyclo[5.4.0]undec-7-ene; In tetrahydrofuran; at 25 ℃; for 16h;

DOI:10.1016/j.tetlet.2013.03.050

Reference yield:

tributyltin chloride (1461-22-9) + sodium salicylate (54-21-7) → tributyltin salicylate (4342-30-7)

Guidance literature:

In benzene; 1:1 mole ratio;

upstream raw materials:

bis(tri-n-butyltin)oxide

salicylic acid

tributyltin chloride

sodium salicylate

Refernces

• 1、 Khawar Rauf,Adeel Saeed,Imtiaz-ud-Din,Bolte,Badshah,Mirza. "Synthesis, characterization and biological activities of some new organotin(IV) derivatives: Crystal structure of [(Sn Ph3) (OOCC6H4OH)] and [(SnMe3)2 (OOC)2C6Cl4 (DMSO)2]". . p. 3043 - 3048. Retrieved 2008/12/21.