(η5-C5Me5)Ir(PMe3)Br2

Base Information

Chemical Name:(η5-C5Me5)Ir(PMe3)Br2
CAS No.:85453-01-6
Molecular Formula:C₁₃H₂₄Br₂IrP
Molecular Weight:563.335
Hs Code.:

Synonyms:(η5-C5Me5)Ir(PMe3)Br2

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Chemical Property of (η5-C5Me5)Ir(PMe3)Br2

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Technology Process of (η5-C5Me5)Ir(PMe3)Br2

There total 1 articles about (η5-C5Me5)Ir(PMe3)Br2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 44.0%

: 80146-01-6
pentamethylcyclopentadienyliridium(III) PMe₃ dihydride

: 75-25-2
Bromoform

: 85453-01-6
(η5-C5Me5)Ir(PMe3)Br2

: (C₅(CH₃)5)Ir(P(CH₃)3)(C₆H₁₁)Br

Guidance literature:: In cyclohexane; Irradiation (UV/VIS); dihydride Ir complex in cyclohexane irradiating for 5 h, solvent removing in vacuo, bromoform adding, after 2 h chromg. on alumina; identified by elem. anal., IR and NMR spectra;
DOI:10.1021/ja00350a031

Reference yield: 50.0%

: 85453-01-6
(η5-C5Me5)Ir(PMe3)Br2

: 100-59-4
phenylmagnesium chloride

: 114378-42-6
(η5-C5Me5)Ir(PMe3)(C6H5)Br

Guidance literature:: In diethyl ether; benzene; dissolving (η5C5Me5)Ir(PMe3)Br2 in minimal amount of benzene, adding diethyl ether, adding dropwise phenyl magnesium chloride, 14 h at ca. 19°C; rapid filtration through pad of silica gel, washing (diethyl ether), concg. soln., chromatography on silica gel (25% diethyl ether/hexane), collecting yellow band, concg. in vacuo, crystn. (toluene/hexane 1:); elem. anal.;
DOI:10.1021/ja00221a026