(2,6-Mes₂C₆H₃)2BiMe

Base Information

• Chemical Name: (2,6-Mes₂C₆H₃)2BiMe
• CAS No.: 298202-61-6
• Molecular Formula: C₄₈H₅₀BiCl
• Molecular Weight: 871.358
• Mol file: 298202-61-6.mol

Synonyms:(2,6-Mes₂C₆H₃)2BiMe

Chemical Property of (2,6-Mes₂C₆H₃)2BiMe

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (2,6-Mes₂C₆H₃)2BiMe

There total 1 articles about (2,6-Mes₂C₆H₃)2BiMe which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 36.0%

bismuth(III) chloride (7787-60-2) + (2,6-dimesitylphenyl)lithium → (2,6-Mes2C6H3)2BiMe (298202-61-6)

Guidance literature:

In toluene; all operations under anaerobic and anhydrous conditions; soln. of org. compd. added dropwise to suspn. of BiCl3 at ca. 0°C, warmed to room temp. and stirred overnight; filtered, solvent evapd. in vac., residue extd. with hexane;

DOI:10.1002/1521-3773(20000804)39:15<2771::AID-ANIE2771>3.0.CO;2-7

Reference yield: 61.0%

(2,6-Mes2C6H3)2BiMe (298202-61-6) → (2,6-Mes2C6H3)2BiH (298202-62-7)

Guidance literature:

With lithium aluminium tetrahydride; In diethyl ether; at -90 - -20 ℃; for 0.5h; Inert atmosphere;

DOI:10.1002/anie.201803160

Reference yield: 29.3%

lithium aluminium tetrahydride (16853-85-3) + (2,6-Mes2C6H3)2BiMe (298202-61-6) → (2,6-Mes2C6H3)2BiH (298202-62-7)

Guidance literature:

In diethyl ether; toluene; all operations under anaerobic and anhydrous conditions; soln. of LiAlH4 in Et2O added to rapidly stirred soln. of Bi compd. in toluene at 0°C, stirred overnight at room temp.; solvent evapd. in vac., residue extd. with benzene, supernatant liquid decanted, pptd. by concn.;

DOI:10.1002/1521-3773(20000804)39:15<2771::AID-ANIE2771>3.0.CO;2-7

upstream raw materials:

bismuth(III) chloride

Downstream raw materials:

(2,6-Mes₂C₆H₃)2BiH

(2,6-Mes₂C₆H₃)2BiD