Bismuthtrichloride

Base Information

• Chemical Name: Bismuthtrichloride
• CAS No.: 7787-60-2
• Molecular Formula: BiCl3
• Molecular Weight: 315.339
• UNII: 4X6566U3SD
• Nikkaji Number: J43.711E
• Mol file: 7787-60-2.mol

Synonyms:BISMUTHTRICHLORIDE;Bismuth chloride [WHO-DD];BISMUTH CHLORIDE [MI];AKOS030228659;B3546

Chemical Property of Bismuthtrichloride

Chemical Property:

• Appearance/Colour: White crystal and crystalline powder
• Melting Point: 230-232 °C(lit.)
• Boiling Point: 447oC
• Flash Point: 430°C
• PSA: 0.00000
• Density: 4.75 g/cm³
• LogP: 2.06850
• Water Solubility.: decomposes
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 0
• Exact Mass: 313.88696
• Heavy Atom Count: 4
• Complexity: 0

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi:Irritant
• Statements: R36/37/38:
• Safety Statements: S26:; S37/39:

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: [Cl-].[Cl-].[Cl-].[Bi+3]

Technology Process of Bismuthtrichloride

There total 124 articles about Bismuthtrichloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

hydrogenchloride (7647-01-0,15364-23-5) + bismuth(III) oxide (1304-76-3) → bismuth(III) chloride (7787-60-2)

Guidance literature:

In acetic acid; byproducts: H2O;

Reference yield: 100.0%

bismuth (7440-69-9) + chlorine (7782-50-5) → bismuth(III) chloride (7787-60-2)

Guidance literature:

In melt; passing a stream of Cl2/inert gas into molten Bi with formation of volatile BiCl3; description of the aparatus given;;

Reference yield: 99.0%

tri(naphthalen-1-yl)bismuth (33397-22-7) → naphthalene (91-20-3,71998-51-1,72931-45-4) + 1-benzoylnaphthalene (642-29-5) + bismuth(III) chloride (7787-60-2)

Guidance literature:

With aluminium trichloride; benzoic acid; In chloroform; 5 h reflux, molar ratio Bi(1-C10H7)3:AlCl3:C6H5COOH = 1:1:1;

upstream raw materials:

trimethylamine hydrochloride

triphenylbismuthane

phosgene

hydrogenchloride

Downstream raw materials:

tris(3-benzyloxyphenyl)bismuthane

bismuth

hydrogenchloride

chlorotriethylstannane

Refernces

Synthesis of new diversely linked biquinoline derivatives by multicomponent Imino-Diels-Alder cycloaddition and intramolecular friedel-crafts cyclization

10.1055/s-0029-1218613

The research focuses on the development of new and efficient routes for synthesizing various types of biquinoline derivatives, specifically 2,6′-, 2,7′-, 2,2′-, and 2,8′-biquinolines. These compounds are of significant interest in organic and medicinal chemistry due to their potential applications in drug development, particularly as anticancer agents, and their role as ligands in coordination chemistry. The synthetic methods employed in this study include imino-Diels–Alder cycloaddition reactions and intramolecular Friedel–Crafts cyclization reactions. Key chemicals involved in the synthesis include simple anilines, benzaldehydes, N-vinylpyrrolidin-2-one (NVP), and various substituted quinolines. The researchers also utilized reagents such as bismuth(III) chloride (BiCl3) for catalysis, sulfur for oxidation, and hydrogenation conditions (H2/Pd/C in methanol) for reduction steps. The study successfully synthesized a range of biquinoline derivatives, with detailed characterization of the products through IR, 1H and 13C NMR spectroscopy, and GC-MS analysis, confirming their structures and yielding insights into their stereochemistry.