N-benzyl-N-[(1S,4S,5S)-7-cyclohexyl-4-[(dibenzo[d,f][1,3,2]dioxaphosphepin-6-yl)oxy]-5-{[(dibenzo[d,f][1,3,2]dioxaphosphepin-6-yl)oxy]methyl}bicyclo[3.2.0]hept-6-en-6-yl]-4-methylbenzenesulfonamide

Base Information

Chemical Name:N-benzyl-N-[(1S,4S,5S)-7-cyclohexyl-4-[(dibenzo[d,f][1,3,2]dioxaphosphepin-6-yl)oxy]-5-{[(dibenzo[d,f][1,3,2]dioxaphosphepin-6-yl)oxy]methyl}bicyclo[3.2.0]hept-6-en-6-yl]-4-methylbenzenesulfonamide
CAS No.:1375102-00-3
Molecular Formula:C₅₂H₄₉NO₈P₂S
Molecular Weight:909.976
Hs Code.:

N-benzyl-N-[(1S,4S,5S)-7-cyclohexyl-4-[(dibenzo[d,f][1,3,2]dioxaphosphepin-6-yl)oxy]-5-{[(dibenzo[d,f][1,3,2]dioxaphosphepin-6-yl)oxy]methyl}bicyclo[3.2.0]hept-6-en-6-yl]-4-methylbenzenesulfonamide

Synonyms:N-benzyl-N-[(1S,4S,5S)-7-cyclohexyl-4-[(dibenzo[d,f][1,3,2]dioxaphosphepin-6-yl)oxy]-5-{[(dibenzo[d,f][1,3,2]dioxaphosphepin-6-yl)oxy]methyl}bicyclo[3.2.0]hept-6-en-6-yl]-4-methylbenzenesulfonamide

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Chemical Property of N-benzyl-N-[(1S,4S,5S)-7-cyclohexyl-4-[(dibenzo[d,f][1,3,2]dioxaphosphepin-6-yl)oxy]-5-{[(dibenzo[d,f][1,3,2]dioxaphosphepin-6-yl)oxy]methyl}bicyclo[3.2.0]hept-6-en-6-yl]-4-methylbenzenesulfonamide

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Technology Process of N-benzyl-N-[(1S,4S,5S)-7-cyclohexyl-4-[(dibenzo[d,f][1,3,2]dioxaphosphepin-6-yl)oxy]-5-{[(dibenzo[d,f][1,3,2]dioxaphosphepin-6-yl)oxy]methyl}bicyclo[3.2.0]hept-6-en-6-yl]-4-methylbenzenesulfonamide

There total 4 articles about N-benzyl-N-[(1S,4S,5S)-7-cyclohexyl-4-[(dibenzo[d,f][1,3,2]dioxaphosphepin-6-yl)oxy]-5-{[(dibenzo[d,f][1,3,2]dioxaphosphepin-6-yl)oxy]methyl}bicyclo[3.2.0]hept-6-en-6-yl]-4-methylbenzenesulfonamide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 61.0%

: 16611-68-0
6-chloro-dibenzo[d,f][1,3,2]-dioxaphosphepin

: 1375101-98-6
N-benzyl-N-[(1S,4S,5S)-7-cyclohexyl-4-hydroxy-5-(hydroxymethyl)bicyclo[3.2.0]hept-6-en-6-yl]-4-methylbenzenesulfonamide

: 1375102-00-3
N-benzyl-N-[(1S,4S,5S)-7-cyclohexyl-4-[(dibenzo[d,f][1,3,2]dioxaphosphepin-6-yl)oxy]-5-{[(dibenzo[d,f][1,3,2]dioxaphosphepin-6-yl)oxy]methyl}bicyclo[3.2.0]hept-6-en-6-yl]-4-methylbenzenesulfonamide

Guidance literature:: With triethylamine; In dichloromethane; at 20 ℃; for 9h; Inert atmosphere;
DOI:10.1055/s-0031-1289679

Reference yield:

: 1116153-61-7
N-benzyl-N-(cyclohexylethynyl)-4-methylbenzenesulfonamide

: 1375102-00-3
N-benzyl-N-[(1S,4S,5S)-7-cyclohexyl-4-[(dibenzo[d,f][1,3,2]dioxaphosphepin-6-yl)oxy]-5-{[(dibenzo[d,f][1,3,2]dioxaphosphepin-6-yl)oxy]methyl}bicyclo[3.2.0]hept-6-en-6-yl]-4-methylbenzenesulfonamide

Guidance literature:: Multi-step reaction with 3 steps

1.1: RuCl2(κ4-N,N'-bis[o-(diphenylphosphino)benzylidene]-(1S,2S)-diiminocyclohexane); triethyloxonium hexaflourophosphate / dichloromethane / 0.17 h / 20 °C / Inert atmosphere

1.2: 24 h / 55 °C / Inert atmosphere

2.1: lithium aluminium tetrahydride / diethyl ether / 2.5 h / 0 - 20 °C / Inert atmosphere

2.2: Inert atmosphere

3.1: triethylamine / dichloromethane / 9 h / 20 °C / Inert atmosphere

With lithium aluminium tetrahydride; RuCl2(κ4-N,N'-bis[o-(diphenylphosphino)benzylidene]-(1S,2S)-diiminocyclohexane); triethyloxonium hexaflourophosphate; triethylamine; In diethyl ether; dichloromethane; 1.1: Ficini reaction / 1.2: Ficini reaction;
DOI:10.1055/s-0031-1289679

Reference yield:

: 1290631-83-2
(1R,5S)-tert-butyl-7-[N-benzyl-4-methylphenylsulfonamido]-6-cyclohexyl-2-oxobicyclo[3.2.0]hept-6-ene-1-carboxylate

: 1375102-00-3
N-benzyl-N-[(1S,4S,5S)-7-cyclohexyl-4-[(dibenzo[d,f][1,3,2]dioxaphosphepin-6-yl)oxy]-5-{[(dibenzo[d,f][1,3,2]dioxaphosphepin-6-yl)oxy]methyl}bicyclo[3.2.0]hept-6-en-6-yl]-4-methylbenzenesulfonamide

Guidance literature:: Multi-step reaction with 2 steps

1.1: lithium aluminium tetrahydride / diethyl ether / 2.5 h / 0 - 20 °C / Inert atmosphere

1.2: Inert atmosphere

2.1: triethylamine / dichloromethane / 9 h / 20 °C / Inert atmosphere

With lithium aluminium tetrahydride; triethylamine; In diethyl ether; dichloromethane;
DOI:10.1055/s-0031-1289679