1-[(5,5-dimethyl-2-thioxo-1,3,2-dioxaphosphorinan-2-yl)disulfanyl]dodecane

Base Information

• Chemical Name: 1-[(5,5-dimethyl-2-thioxo-1,3,2-dioxaphosphorinan-2-yl)disulfanyl]dodecane
• CAS No.: 934499-56-6
• Molecular Formula: C₁₇H₃₅O₂PS₃
• Molecular Weight: 398.635
• Mol file: 934499-56-6.mol

Synonyms:1-[(5,5-dimethyl-2-thioxo-1,3,2-dioxaphosphorinan-2-yl)disulfanyl]dodecane

Chemical Property of 1-[(5,5-dimethyl-2-thioxo-1,3,2-dioxaphosphorinan-2-yl)disulfanyl]dodecane

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1-[(5,5-dimethyl-2-thioxo-1,3,2-dioxaphosphorinan-2-yl)disulfanyl]dodecane

There total 1 articles about 1-[(5,5-dimethyl-2-thioxo-1,3,2-dioxaphosphorinan-2-yl)disulfanyl]dodecane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 57.0%

5,5-dimethyl-2-thiolo-2-thiono-1,3,2-dioxaphosphorinane (697-45-0) + 1-dodecylthiol (112-55-0) → 1-[(5,5-dimethyl-2-thioxo-1,3,2-dioxaphosphorinan-2-yl)disulfanyl]dodecane (934499-56-6) + didodecyl disulfide (2757-37-1) + bis-(5,5-dimethyl-2-thiono-1,3,2-dioxaphosphorinan-2-yl)disulfide (4073-59-0)

Guidance literature:

With 2,3-dicyano-5,6-dichloro-p-benzoquinone; In dichloromethane; at 0 ℃; for 0.0833333h;

DOI:10.1039/c5ra04173b

Reference yield: 100.0%

1-[(5,5-dimethyl-2-thioxo-1,3,2-dioxaphosphorinan-2-yl)disulfanyl]dodecane (934499-56-6) + 5-methylhex-1-yne (2203-80-7) → 1-(dodec-1-ylsulfanyl)-5-methylhex-1-yne

Guidance literature:

5-methylhex-1-yne; With n-butyllithium; N,N,N,N,-tetramethylethylenediamine; In tetrahydrofuran; for 0.0833333h; Inert atmosphere;

1-[(5,5-dimethyl-2-thioxo-1,3,2-dioxaphosphorinan-2-yl)disulfanyl]dodecane; In tetrahydrofuran; at 20 ℃; for 0.5h; Inert atmosphere;

DOI:10.1039/c6ra19440k

Reference yield: 99.0%

1-[(5,5-dimethyl-2-thioxo-1,3,2-dioxaphosphorinan-2-yl)disulfanyl]dodecane (934499-56-6) + thiophenol (108-98-5) → dodecyl phenyl disulfide

Guidance literature:

With triethylamine; In dichloromethane; at 20 ℃; for 0.25h;

DOI:10.1055/s-2007-965873

upstream raw materials:

5,5-dimethyl-2-thiolo-2-thiono-1,3,2-dioxaphosphorinane

1-dodecylthiol

Downstream raw materials:

C₃₂H₅₆OS₂

2-(dodecylsulfanyl)-1-phenylethanone

[(5,5-dimethyl-2-thioxo-1,3,2-dioxaphosphorinan-2-yl)disulfanyl]benzene

didodecyl disulfide