ethyl 1-(diethoxyphosphoryl)-3,4-dimethylcyclohex-3-enecarboxylate

Base Information

• Chemical Name: ethyl 1-(diethoxyphosphoryl)-3,4-dimethylcyclohex-3-enecarboxylate
• CAS No.: 1191041-60-7
• Molecular Formula: C₁₅H₂₇O₅P
• Molecular Weight: 318.35
• Mol file: 1191041-60-7.mol

Synonyms:ethyl 1-(diethoxyphosphoryl)-3,4-dimethylcyclohex-3-enecarboxylate

Chemical Property of ethyl 1-(diethoxyphosphoryl)-3,4-dimethylcyclohex-3-enecarboxylate

Chemical Property:

Purity/Quality:

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MSDS Files:

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Technology Process of ethyl 1-(diethoxyphosphoryl)-3,4-dimethylcyclohex-3-enecarboxylate

There total 1 articles about ethyl 1-(diethoxyphosphoryl)-3,4-dimethylcyclohex-3-enecarboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 64.0%

ethyl 2-diethoxyphosphinoylacrylate (20345-61-3) + 2,3-dimethyl-buta-1,3-diene (513-81-5) → ethyl 1-(diethoxyphosphoryl)-3,4-dimethylcyclohex-3-enecarboxylate (1191041-60-7)

Guidance literature:

With zinc(II) chloride; In diethyl ether; at 25 ℃; for 15h;

DOI:10.1021/jo9017292

Reference yield: 70.0%

ethyl 1-(diethoxyphosphoryl)-3,4-dimethylcyclohex-3-enecarboxylate (1191041-60-7) + benzyl bromide (100-39-0) → ethyl 1-benzyl-3,4-dimethylcyclohex-3-enecarboxylate (1191041-65-2)

Guidance literature:

ethyl 1-(diethoxyphosphoryl)-3,4-dimethylcyclohex-3-enecarboxylate; With naphthalen-1-yl-lithium; In tetrahydrofuran; at -35 ℃; for 0.5h; Inert atmosphere;

benzyl bromide; In tetrahydrofuran; at -35 ℃; for 0.5h;

DOI:10.1021/jo9017292

upstream raw materials:

ethyl 2-diethoxyphosphinoylacrylate

2,3-dimethyl-buta-1,3-diene

Downstream raw materials:

ethyl 1-benzyl-3,4-dimethylcyclohex-3-enecarboxylate