αH-4-(acetoxymethyl)tetradecachlorotriphenylmethane

Base Information

• Chemical Name: αH-4-(acetoxymethyl)tetradecachlorotriphenylmethane
• CAS No.: 101980-92-1
• Molecular Formula: C₂₂H₆Cl₁₄O₂
• Molecular Weight: 798.63
• Mol file: 101980-92-1.mol

Synonyms:αH-4-(acetoxymethyl)tetradecachlorotriphenylmethane

Chemical Property of αH-4-(acetoxymethyl)tetradecachlorotriphenylmethane

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of αH-4-(acetoxymethyl)tetradecachlorotriphenylmethane

There total 2 articles about αH-4-(acetoxymethyl)tetradecachlorotriphenylmethane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

6,6’-((2,3,5,6-tetrachloro-4-methylphenyl)methylene)bis(1,2,3,4,5-pentachlorobenzene) (79839-38-6) → αH-4-(acetoxymethyl)tetradecachlorotriphenylmethane (101980-92-1)

Guidance literature:

Multi-step reaction with 2 steps

1: 95 percent / Br₂ / CCl₄ / 5 h / Irradiation

2: 82 percent / acetic acid / 72 h / Heating

With bromine; In tetrachloromethane; acetic acid;

DOI:10.1021/jo00363a013

Reference yield:

sodium acetate (127-09-3) + 4-(bromomethyl)tetradecachlorotriphenylmethyl radical (81221-80-9) + 6,6'-((4-(bromomethyl)-2,3,5,6-tetrachlorophenyl)methylene)bis(1,2,3,4,5-pentachlorobenzene) (101998-20-3) → αH-4-(acetoxymethyl)tetradecachlorotriphenylmethane (101980-92-1) + 4-(acetoxymethyl)tetradecachlorotriphenylmethyl radical (101981-06-0)

Guidance literature:

In 1,4-dioxane; methanol; at 66 ℃;

DOI:10.1039/c39830000982

Reference yield: 85.0%

αH-4-(acetoxymethyl)tetradecachlorotriphenylmethane (101980-92-1) → 2,3,5,6-tetrachloro-4-(bis(pentachlorophenyl)methyl)-α-hydroxytoluene (101980-98-7)

Guidance literature:

With hydrogenchloride; In 1,4-dioxane; for 21h; Heating;

DOI:10.1021/jo00363a013

upstream raw materials:

sodium acetate

4-(bromomethyl)tetradecachlorotriphenylmethyl radical

6,6'-((4-(bromomethyl)-2,3,5,6-tetrachlorophenyl)methylene)bis(1,2,3,4,5-pentachlorobenzene)

6,6’-((2,3,5,6-tetrachloro-4-methylphenyl)methylene)bis(1,2,3,4,5-pentachlorobenzene)

Downstream raw materials:

2,3,5,6-tetrachloro-4-(bis(pentachlorophenyl)methyl)-α-hydroxytoluene

1,2-ethylenebis(4-tetradecachlorotriphenylmethyl) diradical

αH-tetradecachloro-4-(chloromethyl)triphenylmethane

αH-tetradecachloro-4-(cyanomethyl)triphenylmethane

Refernces

• 1、 Ballester, Manuel,Veciana, Jaime,Riera, Juan,Castaner, Juan,Armet, Olga,Rovira, Concepcion. "The Influence of a Substituent with Free Radical Character (Reverse Effect) on Some Nucleophilic Substitutions involving Benzylic Systems". . p. 982 - 983. Retrieved 2007/10/02.