(E)-N-(1-(4-methoxyphenyl)ethylidene)-4-methylbenzenesulfonamide

Base Information

• Chemical Name: (E)-N-(1-(4-methoxyphenyl)ethylidene)-4-methylbenzenesulfonamide
• CAS No.: 942066-12-8
• Molecular Formula: C₁₆H₁₇NO₃S
• Molecular Weight: 303.382
• Mol file: 942066-12-8.mol

Synonyms:(E)-N-(1-(4-methoxyphenyl)ethylidene)-4-methylbenzenesulfonamide

Chemical Property of (E)-N-(1-(4-methoxyphenyl)ethylidene)-4-methylbenzenesulfonamide

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (E)-N-(1-(4-methoxyphenyl)ethylidene)-4-methylbenzenesulfonamide

There total 6 articles about (E)-N-(1-(4-methoxyphenyl)ethylidene)-4-methylbenzenesulfonamide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

C16H17NO2S → (E)-N-(1-(4-methoxyphenyl)ethylidene)-4-methylbenzenesulfonamide (942066-12-8)

Guidance literature:

With urea hydrogen peroxide adduct; methyltrioxorhenium(VII); In methanol; at 20 ℃; for 0.5h;

DOI:10.1016/j.tetlet.2020.152587

Reference yield: 84.0%

N-(α-methyl-4-methoxybenzylidene)-p-toluenesulfinamide (959865-53-3) → (E)-N-(1-(4-methoxyphenyl)ethylidene)-4-methylbenzenesulfonamide (942066-12-8)

Guidance literature:

With 3-chloro-benzenecarboperoxoic acid; In dichloromethane; at 20 ℃; for 0.0166667h;

DOI:10.1021/ol048005e

Reference yield:

p-tolylsulfinyl amide (6873-55-8) → (E)-N-(1-(4-methoxyphenyl)ethylidene)-4-methylbenzenesulfonamide (942066-12-8)

Guidance literature:

Multi-step reaction with 2 steps

1: Ti(OEt)4 / CH₂Cl₂ / Heating

2: m-CPBA / CH₂Cl₂ / 20 °C

With titanium(IV) tetraethanolate; 3-chloro-benzenecarboperoxoic acid; In dichloromethane;

DOI:10.1002/anie.200600263 DOI:10.1021/jo0700878

upstream raw materials:

N-(α-methyl-4-methoxybenzylidene)-p-toluenesulfinamide

p-tolylsulfinyl amide

1-(4-methoxyphenyl)ethanone

di(p-tolyl) disulfide

Downstream raw materials:

N-[1-(4-methoxyphenyl)ethyl]-p-toluenesulfonamide