di-n-butyl-di-p-vinylphenyltin

Base Information

Chemical Name:di-n-butyl-di-p-vinylphenyltin
CAS No.:74255-79-1
Molecular Formula:C₂₄H₃₂Sn
Molecular Weight:439.228
Hs Code.:

Synonyms:di-n-butyl-di-p-vinylphenyltin

Suppliers and Price of di-n-butyl-di-p-vinylphenyltin

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of di-n-butyl-di-p-vinylphenyltin

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of di-n-butyl-di-p-vinylphenyltin

There total 2 articles about di-n-butyl-di-p-vinylphenyltin which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 60.3%

: 1073-67-2,24991-47-7
4-vinylbenzyl chloride

: 683-18-1
dibutyltin chloride

: 7439-95-4
magnesium

: 74255-80-4
dibutyl-p-styryltin chloride

: 74255-79-1
di-n-butyl-di-p-vinylphenyltin

Guidance literature:: With t-butylcatechol; HCl; In tetrahydrofuran; byproducts: MgCl2; (Ar); Grignard soln. from Mg and styryl chloride was dropped to soln. of tin compd. within 1-1,5 h, t-butylcatechol was added and mixt. stirredovernight; THF was removed in vac., residue taken up in toluene and treated with dild. HCl (ice-cooling), org. phases were concd. and chromd. (silica gel,pentane/ether); 1st fraction yielded Bu2Sn(styryl)2; elem. anal.; 2nd fraction: Bu2Sn(styryl)Cl; elem. anal.;
DOI:10.1016/S0022-328X(00)93423-5

Reference yield:

: 2039-82-9
1-bromo-4-ethenyl-benzene

: 683-18-1
dibutyltin chloride

: 74255-79-1
di-n-butyl-di-p-vinylphenyltin

Guidance literature:: With magnesium; In not given; Sonication; mixt. of tin derivative, Mg turnings, solvent (Et2O or THF) and few drops of organic bromide was sonicated (ultrasound, 47 kHz, 300W), soln. of organic bromide was added; washed with brine, extd. with Et2O, dried over MgSO4, evapd. in vac., column chromy. (neutral alumina or silica gel, petroleum ether);
DOI:10.1016/j.jorganchem.2009.03.030

Reference yield: 89.0%

: 74255-79-1
di-n-butyl-di-p-vinylphenyltin

: 31930-36-6,31930-37-7
ethyl (E)-3-iodopropenoate

: 1174761-22-8
ethyl (2E)-3-(p-vinylphenyl)prop-2-enoate

Guidance literature:: ethyl (E)-3-iodopropenoate; With bis-triphenylphosphine-palladium(II) chloride; In N,N-dimethyl-formamide; for 0.25h; Inert atmosphere;

di-n-butyl-di-p-vinylphenyltin; In N,N-dimethyl-formamide; at 70 ℃; for 12h; Inert atmosphere;
DOI:10.1016/j.jorganchem.2009.03.030