allenylmethylaniline

Base Information

• Chemical Name: allenylmethylaniline
• CAS No.: 90921-20-3
• Molecular Formula: C₁₀H₁₁N
• Molecular Weight: 145.204
• Mol file: 90921-20-3.mol

Synonyms:allenylmethylaniline

Chemical Property of allenylmethylaniline

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of allenylmethylaniline

There total 8 articles about allenylmethylaniline which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 41.0%

trimethyl(propargyl)silane (13361-64-3) + methoxymethylphenylamine (88933-19-1) → C6H4NCH2CHCCH2 (491-35-0) + allenylmethylaniline (90921-20-3) + 4-methylene-1,2,3,4-tetrahydroquinoline (205676-18-2)

Guidance literature:

With titanium tetrachloride; In dichloromethane; at -78 ℃;

DOI:10.3987/COM-97-7943

Reference yield: 41.0%

but-2-ynyltrimethylsilane (18825-29-1) + 1,3,5-triphenylhexahydro-1,3,5-triazine (91-78-1) → C6H4NCH2CHCCH2 (491-35-0) + 3,4-dimethyl-quinoline (2436-92-2) + allenylmethylaniline (90921-20-3)

Guidance literature:

With boron trifluoride diethyl etherate; In dichloromethane; at -78 ℃;

DOI:10.3987/COM-97-7943

Reference yield: 31.0%

trimethyl(propargyl)silane (13361-64-3) + 1,3,5-triphenylhexahydro-1,3,5-triazine (91-78-1) → C6H4NCH2CHCCH2 (491-35-0) + allenylmethylaniline (90921-20-3) + 4-methylene-1,2,3,4-tetrahydroquinoline (205676-18-2)

Guidance literature:

With titanium tetrachloride; In dichloromethane; at -78 ℃;

DOI:10.3987/COM-97-7943

upstream raw materials:

4-chloro-1,2-butadiene

aniline

N-phenyl-1H-benzotriazolyl-1-methanamine

propargyl bromide

Downstream raw materials:

1-phenyl-2,5-dihydro-1H-pyrrole

Refernces

• 1、 Bao, Weiliang,Zhang, Yongmin. "Gallium mediated allylation and propargylation of 1-(α-aminoalkyl)-benzotriazole: An alternative route to homoallylic and homopropargyl amines". . p. 615 - 620. Retrieved 2007/10/03.