[bis(tricyclohexylphosphane)bis(acetonitrile)(vinyl)ruthenium(II)] hexafluorophosphate

Base Information

• Chemical Name: [bis(tricyclohexylphosphane)bis(acetonitrile)(vinyl)ruthenium(II)] hexafluorophosphate
• CAS No.: 349148-94-3
• Molecular Formula: C₄₂H₇₅N₂P₂Ru*F₆P
• Molecular Weight: 916.053
• Mol file: 349148-94-3.mol

Synonyms:[bis(tricyclohexylphosphane)bis(acetonitrile)(vinyl)ruthenium(II)] hexafluorophosphate

Chemical Property of [bis(tricyclohexylphosphane)bis(acetonitrile)(vinyl)ruthenium(II)] hexafluorophosphate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [bis(tricyclohexylphosphane)bis(acetonitrile)(vinyl)ruthenium(II)] hexafluorophosphate

There total 1 articles about [bis(tricyclohexylphosphane)bis(acetonitrile)(vinyl)ruthenium(II)] hexafluorophosphate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

potassium hexafluorophosphate (17084-13-8) + [hydridobis(tricyclohexylphosphane)(vinyldene)chlororuthenium(II)] + acetonitrile (75-05-8,26809-02-9) → [bis(tricyclohexylphosphane)bis(acetonitrile)(vinyl)ruthenium(II)] hexafluorophosphate (349148-94-3)

Guidance literature:

In dichloromethane; acetonitrile; addn. of KPF6 to a soln. of ruthenium complex in CH2Cl2/CH3CN 1:1, stirring for 35 min at room temp.; evapn., extn. with CH2Cl2, evapn., washing with pentane, drying;

DOI:10.1021/om0100737

Reference yield: 97.0%

[bis(tricyclohexylphosphane)bis(acetonitrile)(vinyl)ruthenium(II)] hexafluorophosphate (349148-94-3) + sodium tetrakis[(3,5-di-trifluoromethyl)phenyl]borate (79060-88-1) → [bis(tricyclohexylphosphane)bis(acetonitrile)(vinyl)ruthenium(II)] tetra(3,5-ditrifluoromethylphenyl)borate (349148-99-8)

Guidance literature:

In diethyl ether; reacting ruthenium complex and boron compd. in ether at 0°C;

DOI:10.1021/om0100737

Reference yield: 78.0%

[bis(tricyclohexylphosphane)bis(acetonitrile)(vinyl)ruthenium(II)] hexafluorophosphate (349148-94-3) + sodium tetraphenyl borate (143-66-8) → [bis(tricyclohexylphosphane)bis(acetonitrile)(vinyl)ruthenium(II)] tetraphenylborate (349148-98-7)

Guidance literature:

In methanol;

DOI:10.1021/om0100737

upstream raw materials:

potassium hexafluorophosphate

acetonitrile

Downstream raw materials:

[bis(tricyclohexylphosphane)bis(acetonitrile)(vinyl)ruthenium(II)] tetraphenylborate

[bis(tricyclohexylphosphane)bis(acetonitrile)(vinyl)ruthenium(II)] tetra(3,5-ditrifluoromethylphenyl)borate