[bis(tricyclohexylphosphane)bis(acetonitrile)(vinyl)ruthenium(II)] tetra(3,5-ditrifluoromethylphenyl)borate

Base Information

• Chemical Name: [bis(tricyclohexylphosphane)bis(acetonitrile)(vinyl)ruthenium(II)] tetra(3,5-ditrifluoromethylphenyl)borate
• CAS No.: 349148-99-8
• Molecular Formula: C₃₂H₁₂BF₂₄*C₄₂H₇₅N₂P₂Ru
• Molecular Weight: 1634.31
• Mol file: 349148-99-8.mol

Synonyms:[bis(tricyclohexylphosphane)bis(acetonitrile)(vinyl)ruthenium(II)] tetra(3,5-ditrifluoromethylphenyl)borate

Chemical Property of [bis(tricyclohexylphosphane)bis(acetonitrile)(vinyl)ruthenium(II)] tetra(3,5-ditrifluoromethylphenyl)borate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [bis(tricyclohexylphosphane)bis(acetonitrile)(vinyl)ruthenium(II)] tetra(3,5-ditrifluoromethylphenyl)borate

There total 1 articles about [bis(tricyclohexylphosphane)bis(acetonitrile)(vinyl)ruthenium(II)] tetra(3,5-ditrifluoromethylphenyl)borate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

[bis(tricyclohexylphosphane)bis(acetonitrile)(vinyl)ruthenium(II)] hexafluorophosphate (349148-94-3) + sodium tetrakis[(3,5-di-trifluoromethyl)phenyl]borate (79060-88-1) → [bis(tricyclohexylphosphane)bis(acetonitrile)(vinyl)ruthenium(II)] tetra(3,5-ditrifluoromethylphenyl)borate (349148-99-8)

Guidance literature:

In diethyl ether; reacting ruthenium complex and boron compd. in ether at 0°C;

DOI:10.1021/om0100737

Reference yield: 91.0%

Brookhart's acid + [bis(tricyclohexylphosphane)bis(acetonitrile)(vinyl)ruthenium(II)] tetra(3,5-ditrifluoromethylphenyl)borate (349148-99-8) → [bis(tricyclohexylphosphane)bis(acetonitrile)(methylcarbene)ruthenium(II)] di(tetra(3,5-trifluoromethylphenyl)borate)

Guidance literature:

In dichloromethane; addn. of a soln. of boron compd. in CH2Cl2 to a soln. of ruthenium complex in CH2Cl2 at 0°C, stirring for 5 min, warming to room temp.; evapn., washing with pentane, drying;

DOI:10.1021/om0100737

upstream raw materials:

[bis(tricyclohexylphosphane)bis(acetonitrile)(vinyl)ruthenium(II)] hexafluorophosphate

sodium tetrakis[(3,5-di-trifluoromethyl)phenyl]borate