methyl (1S)-(-)-(1,3,5/2,4)-2,3-diacetoxy-4,5-dibromo-1-cyclohexanecarboxylate

Base Information

Chemical Name:methyl (1S)-(-)-(1,3,5/2,4)-2,3-diacetoxy-4,5-dibromo-1-cyclohexanecarboxylate
CAS No.:108867-00-1
Molecular Formula:C₁₂H₁₆Br₂O₆
Molecular Weight:416.063
Hs Code.:

Synonyms:methyl (1S)-(-)-(1,3,5/2,4)-2,3-diacetoxy-4,5-dibromo-1-cyclohexanecarboxylate

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Chemical Property of methyl (1S)-(-)-(1,3,5/2,4)-2,3-diacetoxy-4,5-dibromo-1-cyclohexanecarboxylate

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Technology Process of methyl (1S)-(-)-(1,3,5/2,4)-2,3-diacetoxy-4,5-dibromo-1-cyclohexanecarboxylate

There total 3 articles about methyl (1S)-(-)-(1,3,5/2,4)-2,3-diacetoxy-4,5-dibromo-1-cyclohexanecarboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 69982-67-8,90695-19-5,115225-39-3
DL-2-exo-bromo-4,8-dioxatricyclo<4.2.1.0^3,7>nonan-5-one

: 104765-18-6,108867-00-1,108867-58-9
methyl DL-(1,3,5/2,4)-2,3-diacetoxy-4,5-dibromocyclohexane-1-carboxylate

Guidance literature:: Multi-step reaction with 2 steps

1: 61 percent / 20percent hydrogen bromide / acetic acid / 48 h / 80 °C / sealed tube

2: 1.) acetyl chloride, 2.) acetic anhydride, pyridine / 1.) reflux, 2 h, 2.) RT

With pyridine; hydrogen bromide; acetic anhydride; acetyl chloride; In acetic acid;
DOI:10.1016/S0008-6215(00)90392-6

Reference yield:

: 67-56-1
methanol

: 104748-84-7,108866-98-4,108866-99-5
DL-(1,3,5/2,4)-2,3-diacetoxy-4,5-dibromocyclohexane-1-carboxylic acid

: 104765-18-6,108867-00-1,108867-58-9
methyl DL-(1,3,5/2,4)-2,3-diacetoxy-4,5-dibromocyclohexane-1-carboxylate

Guidance literature:: With pyridine; acetic anhydride; acetyl chloride; Yield given. Multistep reaction; 1.) reflux, 2 h, 2.) RT;
DOI:10.1016/S0008-6215(00)90392-6

Reference yield:

: 67-56-1
methanol

: 108-24-7
acetic anhydride

: 108866-98-4
(1S,2R,3S,4R,5R)-2,3-Diacetoxy-4,5-dibromo-cyclohexanecarboxylic acid

: 108867-00-1
methyl (1S)-(-)-(1,3,5/2,4)-2,3-diacetoxy-4,5-dibromo-1-cyclohexanecarboxylate

Guidance literature:: With pyridine; acetyl chloride; Yield given. Multistep reaction; 1.) reflux, 2 h, 2.) room temperature;
DOI:10.1246/bcsj.59.2956