[Na-18-crown-6][Fe(SPh)4]

Base Information

Chemical Name:[Na-18-crown-6][Fe(SPh)4]
CAS No.:1092801-16-5
Molecular Formula:C₁₂H₂₄O₆*C₂₄H₂₀FeS₄*Na
Molecular Weight:779.843
Hs Code.:

Synonyms:[Na-18-crown-6][Fe(SPh)4]

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Chemical Property of [Na-18-crown-6][Fe(SPh)4]

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Technology Process of [Na-18-crown-6][Fe(SPh)4]

There total 1 articles about [Na-18-crown-6][Fe(SPh)4] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 43.0%

: 17455-13-9
18-crown-6 ether

: 930-69-8
sodium thiophenolate

: 7705-08-0
iron(III) chloride

: 1092801-16-5
[Na-18-crown-6][Fe(SPh)4]

Guidance literature:: In N,N-dimethyl-formamide; (N2); stirring mixt. of iron compd., sodium benzenethiolate and crown ether in DMF for 30 min at 0°C, stirring for 5 h at room temp.; filtration through celite, addn. of diethyl ether, isolation of ppt., UV;
DOI:10.1021/ja806050x

Reference yield: 73.0%

: 1092801-16-5
[Na-18-crown-6][Fe(SPh)4]

: [Na-18-crown-6]2[Fe₄S₄(nitrosyl)4]

: Na(18-crown-6)[(nitrosyl)2Fe(phenylthiolate)2]

: [Na-18-crown-6]2[Fe₄S₄(SPh)4]

Guidance literature:: In acetonitrile; (N2); addn. of CH3CN soln. of tetra(benzenethiolato)iron(III) compd. to CH3CN soln. of iron compd. at room temp., stirring for 10 min at room temp.; filtration through celite, addn. of diethyl ether, isolation of ppt., evapn. of filtrate, redissolving in THF-diethyl ether, filtration through celite, addn. of hexane, isolation of ppt., IR and UV;
DOI:10.1021/ja806050x

Reference yield:

: 10544-50-0
sulfur

: 1092801-16-5
[Na-18-crown-6][Fe(SPh)4]

: [Na-18-crown-6]2[Fe₄S₃(nitrosyl)7]

: Na(18-crown-6)[(nitrosyl)2Fe(phenylthiolate)2]

: [Na-18-crown-6]2[Fe₄S₄(nitrosyl)4]

: [Na-18-crown-6][Fe₄S₃(nitrosyl)7]

Guidance literature:: In acetonitrile; byproducts: (C6H5S)2; (N2); addn. of CH3CN soln. of tetra(benzenethiolate)iron(III) deriv. to CH3CN soln. of tetrairon compd., addn. to CH3CN soln. of sulfur, stirring at room temp. for 36 h; IR and UV;
DOI:10.1021/ja806050x