14(S),15(R)-epoxyeicosatrienoic acid methyl ester

Base Information

Chemical Name:14(S),15(R)-epoxyeicosatrienoic acid methyl ester
CAS No.:110901-52-5
Molecular Formula:C₂₁H₃₄O₃
Molecular Weight:334.499
Hs Code.:

Synonyms:14(S),15(R)-epoxyeicosatrienoic acid methyl ester

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Chemical Property of 14(S),15(R)-epoxyeicosatrienoic acid methyl ester

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Technology Process of 14(S),15(R)-epoxyeicosatrienoic acid methyl ester

There total 12 articles about 14(S),15(R)-epoxyeicosatrienoic acid methyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 51.6%

: 67-56-1
methanol

: 105304-92-5,81276-03-1
14(S),15(R)-Epoxyeicosatrienoic acid

: 110901-52-5
14(S),15(R)-epoxyeicosatrienoic acid methyl ester

Guidance literature:: 14(S),15(R)-Epoxyeicosatrienoic acid; With β-nicotinamide adenine dinucleotide 2’-phosphate reduced tetrasodium salt; Bacillus megaterium mutant (F₈₇V) P₄₅₀-BM₃; In aq. phosphate buffer; dimethyl sulfoxide; Enzymatic reaction;

methanol; With diazomethyl-trimethyl-silane; In hexane; toluene; for 0.666667h; enantioselective reaction;
DOI:10.1194/jlr.D089136

Reference yield: 45.0%

: 186581-53-3,908094-01-9,334-88-3
diazomethane

: 506-32-1,236743-58-1
all cis 5,8,11,14-eicosatetraenoic acid

: 110901-52-5
14(S),15(R)-epoxyeicosatrienoic acid methyl ester

Guidance literature:: all cis 5,8,11,14-eicosatetraenoic acid; With cytochrome P₄₅₀BM₃ (F₈₇V); potassium carbonate; NADPH; at 20 ℃; for 0.25h; pH=7.4;

diazomethane; In methanol; diethyl ether;
DOI:10.1016/S0040-4039(01)00694-3