2,2',2''-tris<(3,5-bis(trifluoromethyl)phenyl)amino>triethylamine

Base Information

• Chemical Name: 2,2',2''-tris<(3,5-bis(trifluoromethyl)phenyl)amino>triethylamine
• CAS No.: 155019-79-7
• Molecular Formula: C₃₀H₂₄F₁₈N₄
• Molecular Weight: 782.519
• Mol file: 155019-79-7.mol

Synonyms:2,2',2''-tris<(3,5-bis(trifluoromethyl)phenyl)amino>triethylamine

Chemical Property of 2,2',2''-tris<(3,5-bis(trifluoromethyl)phenyl)amino>triethylamine

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2,2',2''-tris<(3,5-bis(trifluoromethyl)phenyl)amino>triethylamine

There total 2 articles about 2,2',2''-tris<(3,5-bis(trifluoromethyl)phenyl)amino>triethylamine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

2,2',2''-triaminotriethylamine (4097-89-6) + 1-fluoro-3,5-bis-(trifluoromethyl)benzene (35564-19-3) → 2,2',2''-tris<(3,5-bis(trifluoromethyl)phenyl)amino>triethylamine (155019-79-7)

Guidance literature:

With potassium carbonate; In dimethyl sulfoxide; at 110 - 120 ℃; for 48h;

DOI:10.1021/ja00089a028

Reference yield:

3,5-Bis-(trifluoromethyl)aniline (328-74-5) → 2,2',2''-tris<(3,5-bis(trifluoromethyl)phenyl)amino>triethylamine (155019-79-7)

Guidance literature:

Multi-step reaction with 2 steps

1: 1.) 6 N hydrochloric acid, aq. sodium nitrite, aq. sodium tetrafluoroborate / 1.) 0 deg C, 15 min, 2.) 200 deg C

2: 99 percent / potassium carbonate / dimethylsulfoxide / 48 h / 110 - 120 °C

With hydrogenchloride; sodium tetrafluoroborate; potassium carbonate; sodium nitrite; In dimethyl sulfoxide;

DOI:10.1021/ja00089a028

Reference yield: 87.0%

tetrakis(dimethylamido)molybdenum(IV) (100207-68-9) + 2,2',2''-tris<(3,5-bis(trifluoromethyl)phenyl)amino>triethylamine (155019-79-7) → Mo(N(CH2CH2NC6H3(CF3)2)3)(N(CH3)2) (155019-62-8)

Guidance literature:

In pentane; byproducts: NH(CH3)2; under exclusion of air; the amine was added to a precooled soln. of the Mo compd. in pentane, stirred at room temp. overnight; filtered, extd. with pentane, combined filtrates were reduced in vol., cooled; elem. anal.;

DOI:10.1021/ja00089a028

upstream raw materials:

2,2',2''-triaminotriethylamine

1-fluoro-3,5-bis-(trifluoromethyl)benzene

3,5-Bis-(trifluoromethyl)aniline

Downstream raw materials:

Mo(N(CH₂CH₂NC₆H₃(CF₃)2)3)(N(CH₃)2)

Refernces