CYCLOPENTADIENYLMOLYBDENUM(II) TRICARBO&

Base Information

• Chemical Name: CYCLOPENTADIENYLMOLYBDENUM(II) TRICARBO&
• CAS No.: 12128-23-3
• Molecular Formula: C8H5 Cl Mo O3
• Molecular Weight: 280.519
• Mol file: 12128-23-3.mol

Synonyms:Molybdenum,chlorotricarbonylcyclopentadienyl- (6CI,7CI); Molybdenum, tricarbonylchloro-p-cyclopentadienyl- (8CI);Chlorotricarbonyl-p-cyclopentadienylmolybdenum; Cyclopentadienylmolybdenum tricarbonylchloride; NSC 101177; Tricarbonyl(cyclopentadienyl)chloromolybdenum;Tricarbonylchloro(h5-cyclopentadienyl)molybdenum; Tricarbonylchloro-p-cyclopentadienylmolybdenum;Tricarbonylchlorocyclopentadienylmolybdenum

Chemical Property of CYCLOPENTADIENYLMOLYBDENUM(II) TRICARBO&

Chemical Property:

• Melting Point: 147 °C(lit.)
• PSA: 0.00000
• LogP: 1.29640

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s): R14:
• Hazard Codes: F
• Statements: 14-14/15
• Safety Statements: 22-26-36-43

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of CYCLOPENTADIENYLMOLYBDENUM(II) TRICARBO&

There total 12 articles about CYCLOPENTADIENYLMOLYBDENUM(II) TRICARBO& which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 72.0%

{Mo(η5-C5H5)(PPh2)(CO)3} + dimethyl acetylenedicarboxylate (762-42-5) → tricarbonylcyclopentadienylmolybdenum(II) chloride (12128-23-3) + {(C5H5)Mo(CO)2((C6H5)2PC(CO2CH3)C(CO2CH3)CO)}

Guidance literature:

In toluene; byproducts: {Cp2Mo2(CO)6}; (N2, Ar); addn. of dimethyl acetylenedicarboxylate to soln. of Mo-comound in toluene at room temp.; stirring for 60 h; chromy. (silica gel/CH2Cl2/hexane/acetone); elem. anal.;

DOI:10.1016/0022-328X(91)86122-7

Reference yield: 54.0%

(η(5)-C5H5)W(CO)3(PPh2) + dimethyl acetylenedicarboxylate (762-42-5) → tricarbonylcyclopentadienylmolybdenum(II) chloride (12128-23-3) + {(C5H5)W(CO)2((C6H5)2PC(CO2CH3)C(CO2CH3)CO)}

Guidance literature:

In toluene; byproducts: {Cp2W2(CO)6}; (N2, Ar); addn. of dimethyl acetylenedicarboxylate to soln. of W-comound in toluene at room temp.; stirring for 60 h; chromy. ( silica gel/CH2Cl2/hexane); recrystn. from ethyl acetate/hexane; elem. anal.;

DOI:10.1016/0022-328X(91)86122-7

Reference yield: 14.0%

tricarbonyl(η-cyclopentadienyl)(2,3,4,5-tetraphenylstibolyl)molybdenum (71252-91-0) → tricarbonylcyclopentadienylmolybdenum(II) chloride (12128-23-3) + 1-chloro-2,3,4,5-tetraphenylstibole

Guidance literature:

With chlorine; In tetrachloromethane; hexane; N2-atmosphere; addn. of Cl2 soln. (in hexane) to soln. of Mo-complex (inCCl4) at -10°C; solvent removal (25°C, 15 mmHg, sublimation (50°C, 0.01 mmHg);

DOI:10.1039/DT9790000814

upstream raw materials:

dimethyl acetylenedicarboxylate

chloro-diphenylphosphine

tributylphosphine

tricarbonyl(η-cyclopentadienyl)(2,3,4,5-tetraphenylstibolyl)molybdenum