Technology Process of diphenylpermethylzirconocene
There total 1 articles about diphenylpermethylzirconocene which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
In
diethyl ether; cyclohexane;
oln. of the complex in diethyl ether was added LiPh in cyclohexane under Ar flush at -78°C; soln. was allowed to come to room temp. with stirring for 4 h.;; diethyl ether was removed in vac.; pentane was condensed into the reaction vessel, soln. was filtered, ppt. was washed by condensing of pentane, dark orange filtrate was concd. and cooled to -78°C; recrystd. from pentane; elem. anal.;;
- Guidance literature:
-
In
toluene;
soln. of the complex in toluene was heated at 100°C for 6 h;; toluene was evapd., pentane was condensed into the reaction vessel; soln. was stirred, warmed to dissolve all product and slowly cooled to -78°C, crystals were collected and dried in vac.; elem. anal.;;
- Guidance literature:
-
With
I2;
In
toluene;
titrn. calorimetric expt.; not isolated, react. was monitored in prior NMR expts.;
DOI:10.1021/ja00231a020
