(2S,3S)-4-(benzyloxy)-2-(tert-butyldiphenylsiloxy)-3-methylbutyl pivalate

Base Information

Chemical Name:(2S,3S)-4-(benzyloxy)-2-(tert-butyldiphenylsiloxy)-3-methylbutyl pivalate
CAS No.:95532-14-2
Molecular Formula:C₃₃H₄₄O₄Si
Molecular Weight:532.795
Hs Code.:

Synonyms:(2S,3S)-4-(benzyloxy)-2-(tert-butyldiphenylsiloxy)-3-methylbutyl pivalate

Suppliers and Price of (2S,3S)-4-(benzyloxy)-2-(tert-butyldiphenylsiloxy)-3-methylbutyl pivalate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of (2S,3S)-4-(benzyloxy)-2-(tert-butyldiphenylsiloxy)-3-methylbutyl pivalate

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of (2S,3S)-4-(benzyloxy)-2-(tert-butyldiphenylsiloxy)-3-methylbutyl pivalate

There total 6 articles about (2S,3S)-4-(benzyloxy)-2-(tert-butyldiphenylsiloxy)-3-methylbutyl pivalate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

: 58479-61-1
tert-butylchlorodiphenylsilane

: 95532-13-1
(2S,3S)-4-(benzyloxy)-2-hydroxy-3-methylbutyl pivalate

: 95532-14-2
(2S,3S)-4-(benzyloxy)-2-(tert-butyldiphenylsiloxy)-3-methylbutyl pivalate

Guidance literature:: With 1H-imidazole; In N,N-dimethyl-formamide; for 48h; Ambient temperature;
DOI:10.1021/jo00209a017

Reference yield:

: 95532-11-9
(2S,3S)-1,4-bis(benzyloxy)-3-methylbutan-2-ol

: 95532-14-2
(2S,3S)-4-(benzyloxy)-2-(tert-butyldiphenylsiloxy)-3-methylbutyl pivalate

Guidance literature:: Multi-step reaction with 6 steps

1: 100 percent / H₂ / 10percent Pd/C / ethanol / 48 h / 25 °C

2: 98 percent / p-TsOH / Ambient temperature

3: 92 percent / NaH / 1,2-dimethoxy-ethane / 18 h / 65 °C

4: 80 percent / amberlite IR-120HCP / ethane-1,2-diol; 1,2-dimethoxy-ethane / 48 h / 45 °C

5: 84 percent / pyridine / 2 h / Ambient temperature

6: 98 percent / imidazole / dimethylformamide / 48 h / Ambient temperature

With pyridine; 1H-imidazole; amberlite IR-120HCP; hydrogen; sodium hydride; toluene-4-sulfonic acid; palladium on activated charcoal; In 1,2-dimethoxyethane; ethanol; ethylene glycol; N,N-dimethyl-formamide;
DOI:10.1021/jo00209a017

Reference yield:

: 74213-64-2
(2S,3S)-erythro-3-methylbutane-1,2,4-triol

: 95532-14-2
(2S,3S)-4-(benzyloxy)-2-(tert-butyldiphenylsiloxy)-3-methylbutyl pivalate

Guidance literature:: Multi-step reaction with 5 steps

1: 98 percent / p-TsOH / Ambient temperature

2: 92 percent / NaH / 1,2-dimethoxy-ethane / 18 h / 65 °C

3: 80 percent / amberlite IR-120HCP / ethane-1,2-diol; 1,2-dimethoxy-ethane / 48 h / 45 °C

4: 84 percent / pyridine / 2 h / Ambient temperature

5: 98 percent / imidazole / dimethylformamide / 48 h / Ambient temperature

With pyridine; 1H-imidazole; amberlite IR-120HCP; sodium hydride; toluene-4-sulfonic acid; In 1,2-dimethoxyethane; ethylene glycol; N,N-dimethyl-formamide;
DOI:10.1021/jo00209a017