95532-13-1

Upstream product

• 59005-41-3 (2R,3S)-4-Benzyloxy-3-methyl-butane-1,2-diol 
• 3282-30-2 pivaloyl chloride 
• 80184-02-7 (2S,3S)-4-(benzyloxy)-3-methyl-1,2-butanediol 
• 95532-11-9 (2S,3S)-1,4-bis(benzyloxy)-3-methylbutan-2-ol 
• 74243-88-2 (βS,4S)-β,2,3-trimethyl-1,3-dioxolane-4-ethanol 
• 74213-64-2 (2S,3S)-erythro-3-methylbutane-1,2,4-triol 
• 95588-29-7 (4S)-4-<(1S)-2-(benzyloxy)-1-methylethyl>-2,2-dimethyl-1,3-dioxolane 

Downstream Products

• 80109-41-7 (2S,3S)-4-(benzyloxy)-2-(tert-butyldiphenylsiloxy)-3-methylbutyraldehyde 
• 80109-43-9 <<(1R,2Z/2E,4S)-1-<(1S)-2-(benzyloxy)-1-methylethyl>-4-<(4S)-2,2-dimethyl-1,3-dioxolan-4-yl>-2-pentenyl>oxy>-tert-butyldiphenylsilane 
• 95532-15-3 (2S,3S)-4-(benzyloxy)-2-(tert-butyldiphenylsiloxy)-3-methyl-2-butanol 
• 95532-20-0 (Z)-(2S,3R,6S)-1-Benzyloxy-2-methyl-6-(S)-oxiranyl-hept-4-en-3-ol 
• 95588-33-3 (E)-(2S,3R,6S)-1-Benzyloxy-2-methyl-6-oxiranyl-hept-4-en-3-ol 
• 95532-14-2 (2S,3S)-4-(benzyloxy)-2-(tert-butyldiphenylsiloxy)-3-methylbutyl pivalate 
• 130740-38-4 (E)-(2S,4S,5R,6S,9R,10S)-11-Benzyloxy-5-methoxy-9-methoxymethoxy-2,6,8,10-tetramethyl-undec-7-ene-1,4-diol 
• 130740-38-4 (E)-(2S,4R,5R,6S,9R,10S)-11-Benzyloxy-5-methoxy-9-methoxymethoxy-2,6,8,10-tetramethyl-undec-7-ene-1,4-diol 
• 130740-50-0 (R)-2-[(2R,3S)-3-((E)-(1R,2S,5R,6S)-7-Benzyloxy-1-methoxy-5-methoxymethoxy-2,4,6-trimethyl-hept-3-enyl)-oxiranyl]-propan-1-ol 
• 130740-50-0 (R)-2-[3-((E)-(1R,2S,5R,6S)-7-Benzyloxy-1-methoxy-5-methoxymethoxy-2,4,6-trimethyl-hept-3-enyl)-oxiranyl]-propan-1-ol 
• 116233-37-5 2-[(E)-1-((1R,2S)-3-Benzyloxy-1-methoxymethoxy-2-methyl-propyl)-1-methyl-but-2-enyloxymethyl]-4,4-dimethyl-4,5-dihydro-oxazole 
• 130740-49-7 (3E,7E)-(2S,5S,6S,9R,10S)-11-Benzyloxy-5-methoxy-9-methoxymethoxy-2,6,8,10-tetramethyl-undeca-3,7-dien-1-ol 
• 116233-42-2 (E)-(1R,2S,5R,6S)-7-Benzyloxy-1-(4,4-dimethyl-4,5-dihydro-oxazol-2-yl)-5-methoxymethoxy-2,4,6-trimethyl-hept-3-en-1-ol 
• 130766-31-3 (2Z,7E)-(4R,5R,6S,9R,10S)-11-Benzyloxy-5-methoxy-9-methoxymethoxy-6,8,10-trimethyl-undeca-2,7-dien-4-ol 

Relevant academic research and scientific papers

SYNTHESIS OF ANTITUMOR ANSAMYCINS. 1. SERIAL SIGMATROPIC CONSTRUCTION OF THE C11-C21 ANSA SUBUNIT OF MACBECIN I

Diol 4, comprising the C11-C21 ansa subunit of the antitumor antibiotic macbecin I, has been prepared by a sequence incorporating sequential Wittig rearrangements to establish the carbon skeleton and remote functionality of the macbecin ansa system.

Total Synthesis of Ionophore Antibiotic X-14547A

A highly stereocontrolled and convergent total synthesis of optically active ionophore antibiotic X-14547A (1) was designed and carried out.Degradative reactions led to the key intermediates 3 and 6, which served as convenient comparison stages.The tetrah