(R)-5-Benzyloxy-4-[(S)-1-((R)-1-benzyloxy-but-3-enyl)-1,4-dimethyl-pent-3-enyloxy]-pent-1-en-3-ol

Base Information

Chemical Name:(R)-5-Benzyloxy-4-[(S)-1-((R)-1-benzyloxy-but-3-enyl)-1,4-dimethyl-pent-3-enyloxy]-pent-1-en-3-ol
CAS No.:663599-91-5
Molecular Formula:C₃₀H₄₀O₄
Molecular Weight:464.645
Hs Code.:

Synonyms:(R)-5-Benzyloxy-4-[(S)-1-((R)-1-benzyloxy-but-3-enyl)-1,4-dimethyl-pent-3-enyloxy]-pent-1-en-3-ol

Suppliers and Price of (R)-5-Benzyloxy-4-[(S)-1-((R)-1-benzyloxy-but-3-enyl)-1,4-dimethyl-pent-3-enyloxy]-pent-1-en-3-ol

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of (R)-5-Benzyloxy-4-[(S)-1-((R)-1-benzyloxy-but-3-enyl)-1,4-dimethyl-pent-3-enyloxy]-pent-1-en-3-ol

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of (R)-5-Benzyloxy-4-[(S)-1-((R)-1-benzyloxy-but-3-enyl)-1,4-dimethyl-pent-3-enyloxy]-pent-1-en-3-ol

There total 9 articles about (R)-5-Benzyloxy-4-[(S)-1-((R)-1-benzyloxy-but-3-enyl)-1,4-dimethyl-pent-3-enyloxy]-pent-1-en-3-ol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

: 1826-67-1
vinyl magnesium bromide

: 663599-85-7
(S)-3-Benzyloxy-2-[(S)-1-((R)-1-benzyloxy-but-3-enyl)-1,4-dimethyl-pent-3-enyloxy]-propan-1-ol

: 663599-91-5
(R)-5-Benzyloxy-4-[(S)-1-((R)-1-benzyloxy-but-3-enyl)-1,4-dimethyl-pent-3-enyloxy]-pent-1-en-3-ol

Guidance literature:: (S)-3-Benzyloxy-2-[(S)-1-((R)-1-benzyloxy-but-3-enyl)-1,4-dimethyl-pent-3-enyloxy]-propan-1-ol; With Dess-Martin periodane;

vinyl magnesium bromide; In tetrahydrofuran;

Reference yield:

: 17123-60-3
2-methylhexa-1,5-dien-3-ol

: 663599-91-5
(R)-5-Benzyloxy-4-[(S)-1-((R)-1-benzyloxy-but-3-enyl)-1,4-dimethyl-pent-3-enyloxy]-pent-1-en-3-ol

Guidance literature:: Multi-step reaction with 8 steps

1.1: 43 percent / (-)-dicyclohexyl tartarate; Ti (OiPr)4; t-BuOOH / CH₂Cl₂

2.1: 87 percent / NaH / tetrahydrofuran

3.1: 86 percent / CuI / tetrahydrofuran / -20 °C

4.1: 87 percent / NaH / tetrahydrofuran

5.1: 85 percent / Me₃CCOCl; Et₃N / tetrahydrofuran / -78 - 0 °C

6.1: 70 percent / NaN(SiMe₃)2 / tetrahydrofuran / -78 °C

7.1: 88 percent / NaBH₄ / tetrahydrofuran; H₂O

8.1: Dess-Martin

8.2: 80 percent / tetrahydrofuran

With titanium(IV) isopropylate; tert.-butylhydroperoxide; sodium tetrahydroborate; copper(l) iodide; (-)-dicyclohexyl D-tartrate; sodium hexamethyldisilazane; pivaloyl chloride; sodium hydride; Dess-Martin periodane; triethylamine; In tetrahydrofuran; dichloromethane; water;

Reference yield:

: 663599-88-0
(R)-1-((S)-2-Methyl-oxiranyl)-but-3-en-1-ol

: 663599-91-5
(R)-5-Benzyloxy-4-[(S)-1-((R)-1-benzyloxy-but-3-enyl)-1,4-dimethyl-pent-3-enyloxy]-pent-1-en-3-ol

Guidance literature:: Multi-step reaction with 7 steps

1.1: 87 percent / NaH / tetrahydrofuran

2.1: 86 percent / CuI / tetrahydrofuran / -20 °C

3.1: 87 percent / NaH / tetrahydrofuran

4.1: 85 percent / Me₃CCOCl; Et₃N / tetrahydrofuran / -78 - 0 °C

5.1: 70 percent / NaN(SiMe₃)2 / tetrahydrofuran / -78 °C

6.1: 88 percent / NaBH₄ / tetrahydrofuran; H₂O

7.1: Dess-Martin

7.2: 80 percent / tetrahydrofuran

With sodium tetrahydroborate; copper(l) iodide; sodium hexamethyldisilazane; pivaloyl chloride; sodium hydride; Dess-Martin periodane; triethylamine; In tetrahydrofuran; water;