Co^III(dimethylglyoximate)₂(4-NMe₂-C₅H₄N)Cl

Base Information

• Chemical Name: Co^III(dimethylglyoximate)₂(4-NMe₂-C₅H₄N)Cl
• CAS No.: 483979-48-2
• Molecular Formula: C₁₅H₂₄ClCoN₆O₄
• Molecular Weight: 446.84
• Mol file: 483979-48-2.mol

Synonyms:Co^III(dimethylglyoximate)₂(4-NMe₂-C₅H₄N)Cl

Chemical Property of Co^III(dimethylglyoximate)₂(4-NMe₂-C₅H₄N)Cl

Chemical Property:

Purity/Quality:

99% ^*data from raw suppliers

Chlorobis(dimethylglyoximato)[4-(dimethylamino)pyridine]cobalt(III) 97% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Co^III(dimethylglyoximate)₂(4-NMe₂-C₅H₄N)Cl

There total 8 articles about Co^III(dimethylglyoximate)₂(4-NMe₂-C₅H₄N)Cl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

dmap (1122-58-3) + dichloro(dimethylglyoxime)(dimethylglyoximato)cobalt(III) → [Co(dimethylglyoximate)(4-(dimethylamino)pyridine)Cl] (483979-48-2)

Guidance literature:

With triethylamine; In methanol; react. Co complex and 4-dimethyaminopyridine (1:1) in MeOH;

DOI:10.1021/ic900389z

Reference yield: 78.0%

dmap (1122-58-3) + cobalt(II) chloride hydrate + butane-2,3-dione dioxime (95-45-4) → CoIII(dimethylglyoximate)2(4-NMe2-C5H4N)Cl (483979-48-2)

Guidance literature:

cobalt(II) chloride hydrate; butane-2,3-dione dioxime; In acetone;

dmap; In methanol; for 0.5h;

DOI:10.1002/chem.202001952

Reference yield: 74.0%

dmap (1122-58-3) + cobalt(II) chloride hexahydrate + butane-2,3-dione dioxime (95-45-4) → CoIII(dimethylglyoximate)2(4-NMe2-C5H4N)Cl (483979-48-2)

Guidance literature:

cobalt(II) chloride hexahydrate; butane-2,3-dione dioxime; With potassium hydroxide; In ethanol; at 80 ℃; for 1h;

dmap;

DOI:10.1055/a-1538-8429

upstream raw materials:

dmap

butane-2,3-dione dioxime

[Co(dimethylglyoxime)2Cl₂]

Downstream raw materials:

dmap

Refernces

• 1、 Wen, Fuyu,Yang, Jinhui,Zong, Xu,Ma, Baojun,Wang, Donge,Li, Can. "Photocatalytic H2 production on hybrid catalyst system composed of inorganic semiconductor and cobaloximes catalysts". . p. 318 - 324. Retrieved 2011.
• 2、 Caldora, Henry P.,Govaerts, Sebastian,Dighe, Shashikant U.,Turner, Oliver J.,Leonori, Daniele. "A de novo Synthesis of Oxindoles from Cyclohexanone-Derived γ-Keto-Ester Acceptors Using a Desaturative Amination-Cyclization Approach". supporting information. p. 4272 - 4278. Retrieved 2021/08/13.
• 3、 Cao, Hui,Jiang, Heming,Feng, Hongyu,Kwan, Jeric Mun Chung,Liu, Xiaogang,Wu, Jie. "Photo-induced Decarboxylative Heck-Type Coupling of Unactivated Aliphatic Acids and Terminal Alkenes in the Absence of Sacrificial Hydrogen Acceptors". supporting information. p. 16360 - 16367. Retrieved 2018/11/27.