trans-dichlorotris(triphenylphosphine)ruthenium(II)

Base Information

Chemical Name:trans-dichlorotris(triphenylphosphine)ruthenium(II)
CAS No.:41756-81-4
Molecular Formula:C₅₄H₄₅Cl₂P₃Ru
Molecular Weight:958.849
Hs Code.:

Synonyms:trans-dichlorotris(triphenylphosphine)ruthenium(II)

Suppliers and Price of trans-dichlorotris(triphenylphosphine)ruthenium(II)

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of trans-dichlorotris(triphenylphosphine)ruthenium(II)

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of trans-dichlorotris(triphenylphosphine)ruthenium(II)

There total 18 articles about trans-dichlorotris(triphenylphosphine)ruthenium(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

: rhodium(III) chloride hydrate

: 603-35-0
triphenylphosphine

: 15529-49-4,41756-81-4
tris(triphenylphosphine)ruthenium(II) chloride

Guidance literature:: In ethanol; for 1h; Reflux; Inert atmosphere;
DOI:10.1021/om400461w

Reference yield: 95.0%

: 14898-67-0
ruthenium(III) chloride trihydrate

: 603-35-0
triphenylphosphine

: 15529-49-4,41756-81-4
tris(triphenylphosphine)ruthenium(II) chloride

Guidance literature:: In methanol; RuCl3*3H2O and PPh3 refluxed in anhyd. MeOH for 2.5 h; according to L. A. Ortiz-Frade et al., Inorg. Chem., 2003, 42, 1825-1834 and P. S. Hallman et al., Inorg. Synth., 1970, 12, 237-240; decanted; solid loaded on Schlenk frit; washed with ether; dried under vac. overnight;;
DOI:10.1021/ic700580u

Reference yield: 94.0%

: 15203-91-5,16904-21-5,13815-94-6,16904-20-4
ruthenium(III)(H₂O)3 chloride

: 603-35-0
triphenylphosphine

: 15529-49-4,41756-81-4
tris(triphenylphosphine)ruthenium(II) chloride

Guidance literature:: In methanol; RuCl3(H2O)3 was dissolved in MeOH, PPh3 was added, heated under reflux for 4 h; filtered, washed with Et2O; elem. anal.;
DOI:10.1021/ic025849q