(Z)-(2-(benzhydryloxy)-1-(2,5-dimethoxyphenyl)ethenyloxy)trimethyl silane

Base Information

Chemical Name:(Z)-(2-(benzhydryloxy)-1-(2,5-dimethoxyphenyl)ethenyloxy)trimethyl silane
CAS No.:866416-81-1
Molecular Formula:C₂₆H₃₀O₄Si
Molecular Weight:434.607
Hs Code.:

Synonyms:(Z)-(2-(benzhydryloxy)-1-(2,5-dimethoxyphenyl)ethenyloxy)trimethyl silane

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Chemical Property of (Z)-(2-(benzhydryloxy)-1-(2,5-dimethoxyphenyl)ethenyloxy)trimethyl silane

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Technology Process of (Z)-(2-(benzhydryloxy)-1-(2,5-dimethoxyphenyl)ethenyloxy)trimethyl silane

There total 1 articles about (Z)-(2-(benzhydryloxy)-1-(2,5-dimethoxyphenyl)ethenyloxy)trimethyl silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 61.0%

: 75-77-4
chloro-trimethyl-silane

: 736933-15-6
2-(benzhydryloxy)-1-(2,5-dimethoxyphenyl)-ethanone

: 866416-81-1
(Z)-(2-(benzhydryloxy)-1-(2,5-dimethoxyphenyl)ethenyloxy)trimethyl silane

Guidance literature:: 2-(benzhydryloxy)-1-(2,5-dimethoxyphenyl)-ethanone; With lithium diisopropyl amide; In tetrahydrofuran; at -78 ℃; for 1h;

chloro-trimethyl-silane; In tetrahydrofuran; at -78 - 20 ℃;
DOI:10.1021/ol051096a

Reference yield:

: 866416-81-1
(Z)-(2-(benzhydryloxy)-1-(2,5-dimethoxyphenyl)ethenyloxy)trimethyl silane

: 866417-02-9
2,5-dimethoxyphenyl 3-acetoxy-2-hydroxy-3-phenylpropanoate

Guidance literature:: Multi-step reaction with 4 steps

1: O⁽⁹⁾-allyl-N-2',3',4'-trifluorobenzylhydrocinchonium*HF₂^(1-) / tetrahydrofuran / 24 h / -55 °C

2: 97 percent / pyridine; DMAP / ethyl acetate / 0 - 20 °C

3: 77 percent / titanium(IV) chloride / CH₂Cl₂ / 2 h / -78 °C

4: 79 percent / K₂CO₃; tin tetrachloride; bis(trimethylsilyl) peroxide / molecular sieves 4 Angstroem; trans-N,N-bis(p-toluenesulfonyl)-1,2-cyclohexanediamine / CH₂Cl₂ / 0.83 h / 0 °C

With pyridine; dmap; bis-trimethylsilanyl peroxide; O⁽⁹⁾-allyl-N-2',3',4'-trifluorobenzylhydrocinchonium*HF₂^(1-); titanium tetrachloride; tin(IV) chloride; potassium carbonate; 4 A molecular sieve; trans-N,N-bis(p-toluenesulfonyl)-1,2-cyclohexanediamine; In tetrahydrofuran; dichloromethane; ethyl acetate; 4: Baeyer-Villiger reaction;
DOI:10.1021/ol051096a

Reference yield:

: 866416-81-1
(Z)-(2-(benzhydryloxy)-1-(2,5-dimethoxyphenyl)ethenyloxy)trimethyl silane

: 124649-67-8
methyl (2S,3R)-3-phenyl-2,3-dihydroxypropanoate

Guidance literature:: Multi-step reaction with 5 steps

1: O⁽⁹⁾-allyl-N-2',3',4'-trifluorobenzylhydrocinchonium*HF₂^(1-) / tetrahydrofuran / 24 h / -55 °C

2: 97 percent / pyridine; DMAP / ethyl acetate / 0 - 20 °C

3: 77 percent / titanium(IV) chloride / CH₂Cl₂ / 2 h / -78 °C

4: 79 percent / K₂CO₃; tin tetrachloride; bis(trimethylsilyl) peroxide / molecular sieves 4 Angstroem; trans-N,N-bis(p-toluenesulfonyl)-1,2-cyclohexanediamine / CH₂Cl₂ / 0.83 h / 0 °C

5: 85 percent / NaOMe / tetrahydrofuran / 0 - 20 °C

With pyridine; dmap; bis-trimethylsilanyl peroxide; O⁽⁹⁾-allyl-N-2',3',4'-trifluorobenzylhydrocinchonium*HF₂^(1-); sodium methylate; titanium tetrachloride; tin(IV) chloride; potassium carbonate; 4 A molecular sieve; trans-N,N-bis(p-toluenesulfonyl)-1,2-cyclohexanediamine; In tetrahydrofuran; dichloromethane; ethyl acetate; 4: Baeyer-Villiger reaction;
DOI:10.1021/ol051096a