N-<(4-chlorophenyl)thio>-2,4,6-triphenylanilino radical

Base Information

• Chemical Name: N-<(4-chlorophenyl)thio>-2,4,6-triphenylanilino radical
• CAS No.: 128529-42-0
• Molecular Formula: C₃₀H₂₁ClNS
• Molecular Weight: 463.022
• Mol file: 128529-42-0.mol

Synonyms:N-<(4-chlorophenyl)thio>-2,4,6-triphenylanilino radical

Chemical Property of N-<(4-chlorophenyl)thio>-2,4,6-triphenylanilino radical

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of N-<(4-chlorophenyl)thio>-2,4,6-triphenylanilino radical

There total 3 articles about N-<(4-chlorophenyl)thio>-2,4,6-triphenylanilino radical which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 18.0%

N-<(4-chlorophenyl)thio>-2,4,6-triphenylaniline (128529-38-4) → N-<(4-chlorophenyl)thio>-2,4,6-triphenylanilino radical (128529-42-0)

Guidance literature:

With potassium carbonate; lead dioxide; In benzene; for 0.0166667h;

DOI:10.1021/jo00023a032

Reference yield:

2,4,6-triphenylaniline (6864-20-6) → N-<(4-chlorophenyl)thio>-2,4,6-triphenylanilino radical (128529-42-0)

Guidance literature:

Multi-step reaction with 2 steps

1: 57 percent / Et₃N / diethyl ether / 2 h / 0 °C

2: 18 percent / PbO₂, K₂CO₃ / benzene / 0.02 h

With potassium carbonate; lead dioxide; triethylamine; In diethyl ether; benzene;

DOI:10.1021/jo00023a032

Reference yield:

4-chloro-benzenesulfenyl chloride (933-01-7) → N-<(4-chlorophenyl)thio>-2,4,6-triphenylanilino radical (128529-42-0)

Guidance literature:

Multi-step reaction with 2 steps

1: 57 percent / Et₃N / diethyl ether / 2 h / 0 °C

2: 18 percent / PbO₂, K₂CO₃ / benzene / 0.02 h

With potassium carbonate; lead dioxide; triethylamine; In diethyl ether; benzene;

DOI:10.1021/jo00023a032

upstream raw materials:

N-<(4-chlorophenyl)thio>-2,4,6-triphenylaniline

2,4,6-triphenylaniline

4-chloro-benzenesulfenyl chloride

Refernces

• 1、 Miura, Yozo,Tanaka, Akio. "Isolation of Exceptionally Persistent Nitrogen-centred Free Radicals: N-Arylthio-2,4,6-triphenylanilino Radicals". . p. 441 - 442. Retrieved 2007/10/02.