6864-20-6

Basic information

• Product Name: 2,4,6-TRIPHENYLANILINE
• Synonyms: 2,4,6-TRIPHENYLANILINE;2,4,6-Triphenylaniline 97%
• CAS NO: 6864-20-6
• Molecular Formula: C₂₄H₁₉N
• Molecular Weight: 321.41
• Product Categories: Amines;C11 to C38;Nitrogen Compounds;Building Blocks;C17 to C40+;Chemical Synthesis;Nitrogen Compounds;Organic Building Blocks
• Mol File: 6864-20-6.mol
• Article Data: 10

Chemical Properties

• Melting Point: 122-125 °C(lit.)
• Boiling Point: 465.4°C at 760 mmHg
• Flash Point: 245.5°C
• Appearance: /
• Density: 1.117g/cm³
• Vapor Pressure: 7.73E-09mmHg at 25°C
• Refractive Index: 1.645
• CAS DataBase Reference: 2,4,6-TRIPHENYLANILINE(CAS DataBase Reference)
• NIST Chemistry Reference: 2,4,6-TRIPHENYLANILINE(6864-20-6)
• EPA Substance Registry System: 2,4,6-TRIPHENYLANILINE(6864-20-6)

Safety Data

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-37/39
• WGK Germany: 3
• Hazardous Substances Data: 6864-20-6(Hazardous Substances Data)

Usage

General Description

2,4,6-Triphenylaniline was oxidized to azo(2,4,6-triphenylbenzene) in acetonitrile containing pyridine.

InChI:InChI=1/C24H19N/c25-24-22(19-12-6-2-7-13-19)16-21(18-10-4-1-5-11-18)17-23(24)20-14-8-3-9-15-20/h1-17H,25H2

Upstream product

• 10368-47-5 2-nitro-1,3,5-triphenyl-benzene 
• 874-17-9 4-chloro-2,6-dibromoaniline 
• 98-80-6 phenylboronic acid 
• 448-61-3 2,4,6-triphenylpyrylium tetrafluoroborate 
• 612-71-5 1,3,5-triphenylbenzene 
• 147-82-0 2,4,6-tribromoaniline 

Downstream Products

• 1608462-69-6 N-([1,1'-biphenyl]-4-yl)-5'-phenyl-N-(4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl)-[1,1':3',1-terphenyl]-2'-amine 
• 1608462-67-4 N-([1,1'-biphenyl]-4-yl)-N-(4-methoxyphenyl)-5'-phenyl-[1,1':3',1-terphenyl]-2'-amine 
• 1391738-90-1 (2,4-bis(2,4,6-triphenylphenylimido)-3-pentyl)Li(OEt₂) 
• 1010100-63-6 (2'-Me₃SiCH₂-4,4',4''-tri-tert-butyl-2,2':6',2''-terpyridine^(1-))lutetium(III)(2,4,6-triphenylanilide)(CH₂SiMe₃) 
• 14347-41-2 N-Phenyl-N'--harnstoff 
• 10384-15-3 2,4,6-triphenyl-4-(2,4,6-triphenyl-phenoxy)-cyclohexa-2,5-dienone 
• 128529-44-2 N-[(2,4-dichlorophenyl)thio]-2,4,6-triphenylanilino radical 
• 128529-43-1 N-<(4-bromophenyl)thio>-2,4,6-triphenylanilino radical 
• 128529-42-0 N-<(4-chlorophenyl)thio>-2,4,6-triphenylanilino radical 
• 97388-42-6 3',5'-diphenyl-p-quaterphenyl 

Relevant articles and documents

NOVEL COMPOUND AND ORGANIC ELECTROLUMINESCENT DIVICE INCLUDING THE SAME

The present invention relates to a novel arylamine compound, which facilitates hole injection and hole transport, thereby exhibiting effects of low voltage and low power consumption. In addition, the novel arlyamine compound exhibits high efficiency by having high LUMO, which enables electronic blocking, due to a wide band gap and can increase thermal stability through Tg rise by increasing robustness in a molecule, thereby stabilizing the life of a device.COPYRIGHT KIPO 2019

Facile synthesis of mono-, bis- and tris-aryl-substituted aniline derivatives in aqueous DMF

A facile, efficient and general protocol for synthesizing a series of mono-, bis- and tris-arylsubstituted aniline derivatives is described via the Pd(OAc)2-catalyzed aerobic and ligand-free Suzuki reaction of mono-, di- and tribromoanilines with aryl boronic acids in aqueous N,Ndimethylformamide (DMF). This is the first example to prepare 2,6-bisaryl-4-nitroanilines and 2,6-bisarylanilines via a palladium-catalyzed ligand-free Suzuki reaction.

Enantioselective organocatalytic Biginelli reaction: Dependence of the catalyst on sterics, hydrogen bonding, and reinforced chirality

From a systematic investigation involving the synthesis of a series of catalysts and screening studies, the organocatalyst 16, which is sterically hindered, contains a strong hydrogen-bonding site, and is endowed with reinforced chirality, is shown to pro