bischlorophosphorus

Base Information

Chemical Name:bischlorophosphorus
CAS No.:63429-87-8
Molecular Formula:C₁₄H₃₈ClPSi₄
Molecular Weight:385.224
Hs Code.:

bis<bis(trimethylsilyl)methyl>chlorophosphorus

Synonyms:bischlorophosphorus

Suppliers and Price of bischlorophosphorus

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of bischlorophosphorus

Chemical Property:

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Technology Process of bischlorophosphorus

There total 1 articles about bischlorophosphorus which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 89178-74-5
(1,5-cyclooctadiene)chloro{bis{bis(trimethylsilyl)methyl}chlorophosphine}rhodium(I)

: 12092-47-6
di-μ-chloro-bis(1,5-cyclooctadiene)dirhodium

: 63429-87-8
bischlorophosphorus

Guidance literature:: In benzene-d6; dissolution in benzene; free phosphine is present in 32% to total phosphorus content at 21°C and ca. 45% at 80°C, shift of the equil. upon addn. of 1 equiv of phosphine ligand or (RhCl(COD))2 confirmes the reversibility of the reaction; (31)P and (1)H NMR spectral data;

Reference yield: 54.0%

: 12092-47-6
di-μ-chloro-bis(1,5-cyclooctadiene)dirhodium

: 63429-87-8
bischlorophosphorus

: 108-88-3,15644-74-3,16713-13-6
toluene

: 89178-74-5
(1,5-cyclooctadiene)chloro{bis{bis(trimethylsilyl)methyl}chlorophosphine}rhodium(I)-toluene

Guidance literature:: In toluene; phosphine was added to a toluene soln. of (RhCl(COD))2 at 25°C under inert atmosphere, mixt. was stirred for 12 h; volatiles were removed in vacuo, toluene and hexane were added, mixt. was filtered though a Celite pad, concd., filtered again, filtrate cooled to -20°C, crystn.;