C₅₇H₈₇ClN₂O₁₂Si₃

Base Information

Chemical Name:C₅₇H₈₇ClN₂O₁₂Si₃
CAS No.:253189-26-3
Molecular Formula:C₅₇H₈₇ClN₂O₁₂Si₃
Molecular Weight:1112.03
Hs Code.:

C<sub>57</sub>H<sub>87</sub>ClN<sub>2</sub>O<sub>12</sub>Si<sub>3</sub>

Synonyms:C₅₇H₈₇ClN₂O₁₂Si₃

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Chemical Property of C₅₇H₈₇ClN₂O₁₂Si₃

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Technology Process of C₅₇H₈₇ClN₂O₁₂Si₃

There total 20 articles about C₅₇H₈₇ClN₂O₁₂Si₃ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 47.0%

: 253189-24-1
C₅₇H₈₈ClIN₂O₁₂Si₃

: 253189-26-3
C₅₇H₈₇ClN₂O₁₂Si₃

Guidance literature:: With copper(l) iodide; N-ethyl-N,N-diisopropylamine; tris(dibenzylideneacetone)dipalladium⁽⁰⁾ chloroform complex; In N,N-dimethyl-formamide; at 20 ℃; for 1h;
DOI:10.1039/b705932a

Reference yield:

: 994-30-9
triethylsilyl chloride

: 253189-26-3
C₅₇H₈₇ClN₂O₁₂Si₃

Guidance literature:: Multi-step reaction with 2 steps

1: 99 percent / imidazole / dimethylformamide

2: 45 percent / CuI; i-Pr₂NEt / Pd₂(dba)3*CHCl₃ / dimethylformamide / 0.5 h / 20 °C

With 1H-imidazole; copper(l) iodide; N-ethyl-N,N-diisopropylamine; tris(dibenzylideneacetone)dipalladium⁽⁰⁾ chloroform complex; In N,N-dimethyl-formamide; 1: silylation / 2: Sonogashira coupling;
DOI:10.1016/S0040-4039(99)01744-X

Reference yield:

: 253189-14-9
(4S,5R)-2-Iodo-4,5-bis-methoxymethoxy-cyclopent-2-enone

: 253189-26-3
C₅₇H₈₇ClN₂O₁₂Si₃

Guidance literature:: Multi-step reaction with 19 steps

1: n-BuLi / tetrahydrofuran / -85 - 20 °C

2: 61 percent / HClO₄ / tetrahydrofuran; H₂O

3: 91 percent / Et₃N; DMAP / CH₂Cl₂

4: 74 percent / PPTS / butan-2-one / Heating

5: 96 percent / imidazole / dimethylformamide

6: 97 percent / PPTS / CH₂Cl₂

7: 85 percent / TBAF / tetrahydrofuran / -40 °C

8: 98 percent / K₂CO₃ / methanol

9: DIAD; PPh₃ / toluene

10: pyridine

11: CsF / dimethylformamide / 60 °C

12: imidazole / dimethylformamide / 50 °C

13: 91 percent / K₂CO₃ / methanol

14: 93 percent / PPTS / methanol

15: 90 percent / PPTS / dimethylformamide

16: 96 percent / H₂O; KOH / tetrahydrofuran; methanol

17: 75 percent / EDC*HCl; DMAP / CH₂Cl₂

18: 99 percent / imidazole / dimethylformamide

19: 45 percent / CuI; i-Pr₂NEt / Pd₂(dba)3*CHCl₃ / dimethylformamide / 0.5 h / 20 °C

With pyridine; 1H-imidazole; dmap; potassium hydroxide; copper(l) iodide; n-butyllithium; perchloric acid; di-isopropyl azodicarboxylate; tetrabutyl ammonium fluoride; water; pyridinium p-toluenesulfonate; potassium carbonate; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride; triethylamine; N-ethyl-N,N-diisopropylamine; triphenylphosphine; cesium fluoride; tris(dibenzylideneacetone)dipalladium⁽⁰⁾ chloroform complex; In tetrahydrofuran; methanol; dichloromethane; water; N,N-dimethyl-formamide; toluene; butanone; 1: Addition / 2: Ring cleavage / 3: Acetylation / 4: ether cleavage; rearrangement / 5: silylation / 6: Addition / 7: desilylation / 8: Deacetylation / 9: Cyclization / 10: Acetylation / 11: Addition / 12: silylation / 13: Deacetylation / 14: ether cleavage / 15: Substitution / 16: Hydrolysis / 17: Esterification / 18: silylation / 19: Sonogashira coupling;
DOI:10.1016/S0040-4039(99)01744-X