[bis(p-tolylimido)-bis(diethyl dithiophosphato)-(μ-acetato)-dimolybdenum(V)-(μ-SBn)-(μ-SOEt)]OTf

Base Information

Chemical Name:[bis(p-tolylimido)-bis(diethyl dithiophosphato)-(μ-acetato)-dimolybdenum(V)-(μ-SBn)-(μ-SOEt)]OTf
CAS No.:1159216-26-8
Molecular Formula:CF₃O₃S*C₃₂H₄₇Mo₂N₂O₇P₂S₆
Molecular Weight:1167.03
Hs Code.:

Synonyms:[bis(p-tolylimido)-bis(diethyl dithiophosphato)-(μ-acetato)-dimolybdenum(V)-(μ-SBn)-(μ-SOEt)]OTf

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Chemical Property of [bis(p-tolylimido)-bis(diethyl dithiophosphato)-(μ-acetato)-dimolybdenum(V)-(μ-SBn)-(μ-SOEt)]OTf

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Technology Process of [bis(p-tolylimido)-bis(diethyl dithiophosphato)-(μ-acetato)-dimolybdenum(V)-(μ-SBn)-(μ-SOEt)]OTf

There total 1 articles about [bis(p-tolylimido)-bis(diethyl dithiophosphato)-(μ-acetato)-dimolybdenum(V)-(μ-SBn)-(μ-SOEt)]OTf which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: 176799-53-4,176897-18-0,176897-19-1,176897-20-4
[Mo2(N-p-tolyl)2(S2P(OEt)2)2(μ-SCH2Ph)(μ-SO)]

: 333-27-7
methyl trifluoromethanesulfonate

: 1159216-26-8
[bis(p-tolylimido)-bis(diethyl dithiophosphato)-(μ-acetato)-dimolybdenum(V)-(μ-SBn)-(μ-SOEt)]OTf

Guidance literature:: In dichloromethane; (N2) to soln. Mo complex in CH2Cl2 CF3SO3Me was added, stirred for 4 min; soln. was evapd. in vacuo, residue was dissolved in EtOH, water was added, stirred for 1.4 h, ppt. was filtered and washed with EtOH/H2O (1:3), suction-dried - mixt. invertomer;
DOI:10.1021/ic9002093

Reference yield: 72.0%

: 1159216-26-8
[bis(p-tolylimido)-bis(diethyl dithiophosphato)-(μ-acetato)-dimolybdenum(V)-(μ-SBn)-(μ-SOEt)]OTf

: 1159216-31-5
bis(p-tolylimido)-bis(diethyl dithiophosphato)-(μ-acetato)-dimolybdenum(V)-(μ-S)-(μ-SOMe)

Guidance literature:: With [PPN]I; In tetrahydrofuran; acetone; to soln. Mo complex in acetone-THF PPNI was added, stirred for 4 min; EtOH/H2O (1:1) was added, ppt. was filtered and was washed with EtOH/H2O(2:1), suction-dried - mixt. invertomers;
DOI:10.1021/ic9002093