[Mo2(N-p-tolyl)2(S2P(OEt)2)2(μ-SCH2Ph)(μ-SO)]

Base Information

Chemical Name:[Mo2(N-p-tolyl)2(S2P(OEt)2)2(μ-SCH2Ph)(μ-SO)]
CAS No.:176799-53-4
Molecular Formula:C₃₁H₄₄Mo₂N₂O₇P₂S₆
Molecular Weight:1002.92
Hs Code.:

Synonyms:

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Chemical Property of [Mo2(N-p-tolyl)2(S2P(OEt)2)2(μ-SCH2Ph)(μ-SO)]

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Technology Process of [Mo2(N-p-tolyl)2(S2P(OEt)2)2(μ-SCH2Ph)(μ-SO)]

There total 2 articles about [Mo2(N-p-tolyl)2(S2P(OEt)2)2(μ-SCH2Ph)(μ-SO)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

: 220390-06-7,103383-36-4
[Mo2(N-p-tolyl)2(S2P(OEt)2)2(μ-SCH2Ph)(μ-S)]

: 937-14-4
3-chloro-benzenecarboperoxoic acid

: 176799-53-4,176897-18-0,176897-19-1,176897-20-4
[Mo2(N-p-tolyl)2(S2P(OEt)2)2(μ-SCH2Ph)(μ-SO)]

: 176799-54-5,177019-12-4
bis(p-tolylimido)-bis(diethyl dithiophosphato)-(μ-acetato)-dimolybdenum(V)-(μ-SBn)-(μ-SO2)

Guidance literature:: With HBF₄; acetic acid; In acetone; byproducts: ClC6H4COOH; to chilled in ice-bath soln. Mo complex in acetone were added dropwise AcOH, 48 aq. HBF4 and chilled soln. m-ClC6H4CO3H in acetone, stirred for 3 min, aq. soln. NaHCO3 was added, stirred for 5 min, ppt. was filtered and washed with acetone-water; chromy. on silica (CH2Cl2);
DOI:10.1021/ic9002093

Reference yield: 75.0%

: 220390-06-7,103383-36-4
[Mo2(N-p-tolyl)2(S2P(OEt)2)2(μ-SCH2Ph)(μ-S)]

: 937-14-4
3-chloro-benzenecarboperoxoic acid

: 176897-18-0,176799-53-4,176897-20-4,176897-19-1
[Mo2(N-p-tolyl)2(S2P(OEt)2)2(μ-SCH2Ph)(μ-SO)]

Guidance literature:: In dichloromethane; byproducts: 3-ClC6H4CO2H; under red light; quick addn. of excess oxidant to Mo-complex (cooling inCH2Cl2-slush bath), warming to -20°C; evapn. (reduced pressure), dissoln. in MeCN, chromy. (SiO2, MeCN), evapn. (reduced pressure), dissoln. in THF, pptn. with 40% aq. EtOH, collection (filtration), drying (vac.); isomer mixt. not sepd., detd. by NMR spectroscopy;
DOI:10.1021/ic951518k

Reference yield: 99.0%

: 176799-53-4,176897-18-0,176897-19-1,176897-20-4
[Mo2(N-p-tolyl)2(S2P(OEt)2)2(μ-SCH2Ph)(μ-SO)]

: 1159216-35-9
(Mo(CH₃C₆H₄N))2((CH₃CH₂O)2PS₂)(CH₃CH₂OPOS₂)CH₃COO(SOCH₃CH₂)(C₆H₅CH₂S)

Guidance literature:: In neat (no solvent, solid phase); Mo complex was heated in boiling-water bath for 150 min; mixt. isomers;
DOI:10.1021/ic9002093