(mesityl)(2,4,6-tris{bis(trimethylsilyl)methyl}phenyl)dihydrostannane

Base Information

Chemical Name:(mesityl)(2,4,6-tris{bis(trimethylsilyl)methyl}phenyl)dihydrostannane
CAS No.:135139-80-9
Molecular Formula:C₃₆H₇₂Si₆Sn
Molecular Weight:792.191
Hs Code.:

Synonyms:(mesityl)(2,4,6-tris{bis(trimethylsilyl)methyl}phenyl)dihydrostannane

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (mesityl)(2,4,6-tris{bis(trimethylsilyl)methyl}phenyl)dihydrostannane

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Technology Process of (mesityl)(2,4,6-tris{bis(trimethylsilyl)methyl}phenyl)dihydrostannane

There total 2 articles about (mesityl)(2,4,6-tris{bis(trimethylsilyl)methyl}phenyl)dihydrostannane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 57.0%

: 16853-85-3
lithium aluminium tetrahydride

: 135139-65-0
2,4,6-tris[bis(trimethylsilyl)methyl]phenyl-trichloro stannane

: 2633-66-1
2-mesitylmagnesium bromide

: 135139-80-9
(mesityl)(2,4,6-tris{bis(trimethylsilyl)methyl}phenyl)dihydrostannane

Guidance literature:: With ethyl acetate; In tetrahydrofuran; addn. of stannane (1.29mmol) in THF to a soln. of mesitylMgBr (prepared from 1.0mmol mesitylBr/1.0mmol Mg) in THF; refluxing, 10h; allowing to cool to room temp.; addn. of LiAlH4; stirring, 3h; addn. of ethyl acetate (quenching react.);; removal ot solvent; addn. of hexane (to precipitate inorganic salts); DCC (hexane) of resulting filtrate;;
DOI:10.1021/om00028a059

Reference yield:

: 115160-05-9
1-bromo-2,4,6-tris[bis(trimethylsilyl)methyl]benzene

: 135139-80-9
(mesityl)(2,4,6-tris{bis(trimethylsilyl)methyl}phenyl)dihydrostannane

Guidance literature:: Multi-step reaction with 2 steps

1: t-C₄H₉Li / tetrahydrofuran

2: ethyl acetate / tetrahydrofuran

With t-C₄H₉Li; ethyl acetate; In tetrahydrofuran;
DOI:10.1021/om00028a059

Reference yield: 100.0%

: 135139-80-9
(mesityl)(2,4,6-tris{bis(trimethylsilyl)methyl}phenyl)dihydrostannane

: 7726-95-6
bromine

: dibromo(mesityl){2,4,6-tris{bis(trimethylsilyl)methyl}phenyl}stannane

Guidance literature:: In diethyl ether; addn. of bromine to an ether soln. of stannane at room temp.; stirring, 10h, crystn.;; removal of solvent; recrystn. from ethanol; elem. anal.;;
DOI:10.1021/om00028a059