Technology Process of Silane, [(2-bromo-1,3,5-benzenetriyl)trimethylidyne]hexakis[trimethyl-
There total 1 articles about Silane, [(2-bromo-1,3,5-benzenetriyl)trimethylidyne]hexakis[trimethyl- which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
bromine;
In
tetrachloromethane;
- Guidance literature:
-
1-bromo-2,4,6-tris[bis(trimethylsilyl)methyl]benzene;
With
tert.-butyl lithium;
In
tetrahydrofuran;
at -78 ℃;
for 0.5h;
Inert atmosphere;
trimethoxysilane;
In
tetrahydrofuran;
at 20 ℃;
Inert atmosphere;
DOI:10.3987/COM-12-S(N)114
- Guidance literature:
-
With
tert-butyllithium; triethylamine;
In
tetrahydrofuran; methanol; pentane;
under Ar; t-BuLi/pentane added to soln. of the bromide in THF at -78°C, stirred for 0.5 h, GeCl4 added at -78°C, warmed to room temp., MeOH and Et3N added, heated under reflux for 2 h; solvents were removed, hexane and water added to residue, extracted withhexane several times, combined organic layers dried over MgSO4, filtere d, solvent was removed in vacuo; elem. anal.;
DOI:10.1021/ja0262941
