[(Z)-2-ethylsulfanyl-vinyl]sulfanyl-ethane

Base Information

• Chemical Name: [(Z)-2-ethylsulfanyl-vinyl]sulfanyl-ethane
• CAS No.: 14044-67-8
• Molecular Formula: C₆H₁₂S₂
• Molecular Weight: 148.293
• DSSTox Substance ID: DTXSID201307699

Synonyms:14044-68-9;14044-67-8;[(Z)-2-ethylsulfanyl-vinyl]sulfanyl-ethane;cis-1,2-diethylthioethene;(1Z)-1,2-Bis(ethylthio)ethene;DTXSID201307699

Chemical Property of [(Z)-2-ethylsulfanyl-vinyl]sulfanyl-ethane

Chemical Property:

• XLogP3: 2.3
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 4
• Exact Mass: 148.03804273
• Heavy Atom Count: 8
• Complexity: 51.5

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCSC=CSCC
• Isomeric SMILES: CCS/C=C\SCC

Technology Process of [(Z)-2-ethylsulfanyl-vinyl]sulfanyl-ethane

There total 1 articles about [(Z)-2-ethylsulfanyl-vinyl]sulfanyl-ethane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

1,1,2-tris-ethylsulfanyl-ethane (7038-14-4) → (Z)-1,2-bis(ethylthio)ethene (14044-67-8) + (E)-1,2-bis(ethylthio)ethene (14044-68-9) + ethanethiol (75-08-1)

Guidance literature:

With toluene-4-sulfonic acid;

Reference yield:

ethyl bromide (74-96-4) + (Z)-1,2-bis(ethylthio)ethene (14044-67-8) → 1-Aethylmercapto-butin-(1) (24298-52-0)

Guidance literature:

Multistep reaction; (i) NaNH₂, liq. NH₃, (ii) /BRN= 1209224/;

DOI:10.1021/jo01349a018

Reference yield:

(Z)-1,2-bis(ethylthio)ethene (14044-67-8) → bis-ethylsulfanyl-acetaldehyde (42919-45-9)

Guidance literature:

With oxygen; rose bengal; In acetone; Irradiation;

DOI:10.1016/S0040-4020(01)83391-3

upstream raw materials:

1,1,2-tris-ethylsulfanyl-ethane

Downstream raw materials:

1-Aethylmercapto-butin-(1)

bis-ethylsulfanyl-acetaldehyde

(Z)-2,3-Bis-ethylsulfanyl-1-phenyl-prop-2-en-1-ol

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